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>Syntheses and electric conductivities of poly(methyl vinyl ketone‐co‐acryl amide)s reacted with phosphorus oxychloride
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Syntheses and electric conductivities of poly(methyl vinyl ketone‐co‐acryl amide)s reacted with phosphorus oxychloride
AbstractStudies have been made on the conductivities of poly(methyl vinyl ketone‐co‐acryl amide) poly(MVK‐co‐AAm)s after having reacted with phosphorus oxychloride. It was found that the conductivities were dependent on the mol ratio of AAmto MVK, copolymerization temperature, and time. The effect of treatment conditions of POCl3on the conductivities of the poly(MVK‐co‐AAm)s was shown to be significant. It was observed that the conductivities of the poly(MVK‐co‐AAm)s, treated with POCl3, are of the order of 10−6–10−9Scm−1. The maximum conductivity of the POCl3‐treated poly(MVK‐co‐AAm) was obtained as 8.7 X 10−6Scm−1when the mol ratio of AAm to MVK was 0.5. The conductivity of the poly(MVK‐co‐AAm) was increased with the treatment time and concentrations
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机译：摘要 研究了聚（甲基乙烯基酮-co-丙烯酰胺）[poly（MVK-co-AAm）]s与三氯氧磷反应后的电导率.结果表明，电导率取决于[AAm]与[MVK]的摩尔比、共聚温度和时间。POCl3处理条件对poly（MVK‐co‐AAm）s电导率的影响显著。观察到用POCl3处理的poly（MVK-co-AAm）s的电导率约为10−6–10−9Scm−1。当AAm与MVK的摩尔比为0.5时，POCl3处理的poly（MVK‐co‐AAm）的最大电导率为8.7 X 10−6Scm−1。聚（MVK-co-AAm）的电导率随处理时间和浓度的增加而增加
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