Preparation and properties of UV‐autocurable BTDA‐based epoxy‐multiacrylate resins. Effects of the degree of polymerization and the epoxy type

摘要

AbstractA series of UV‐autocurable epoxy‐multiacrylate resins was synthesized, and the effects of degree of polymerization (DP) and epoxy type on their properties were investigated. These autocurable multiacrylate resins possess good pot life and are cured rapidly when exposed to ultraviolet (UV) without the addition of photoinitiator or photosensitizer. The curing rate of the autocurable resins was probably dependent on the number of abstractable hydrogen in epoxy resins. Stress‐strain, differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) were used to characterize the properties of cured multiacrylate resins. Increased crosslinking density of cured films improved tensile properties. Increasing the molar ratio of epoxy resin in the multiacrylate resins was found to decrease the effective acrylate concentration of resins and to depress crosslinking density of cured resins, which also resulted in an increased elongation at break but a decreased Young's modulus and breaking strength. Furthermore, the different structures of epoxy resins were used to give wide range properties of cured epoxy‐multiacrylate resins with a glass transition temperature (Tgrange from 74 to 102°C. The film properties of the multiacrylate resins coated on steel plates were also inve