Photochemical Preparation of Pentahapto-cyclopentadienyl Molybdenum Dicarbonyl Nitrosyl

摘要

An efficient photochemical synthesis of n5-cyclopentadienyl molybdenum dicarbonyl nitrosyl employing n5-cyclopentadienyl molybdenum tricarbonyl dimer is described. The mechanism of this transformation is discussed and a path via a triply-bonded dimer implicated.