Geographical trends in levels of ΣPCB{sub}10 (sum of 10 major congeners), hexachlorocyclohexanes (HCH), ΣDDT (sum of DDT-related compounds), and other persistent organochlorines (OCs) in ringed seal blubber were examined at 13 sampling locations in the Arctic over 175 deg longitude from northern Canada to the South Kara Sea (Yenisey Gulf) in Russia. Concentrations of OCs were adjusted, using analysis of covariance, for effects of the covariates, sex, age, and blubber thickness. Adjusted mean concentrations of ΣPCB{sub}10 and ΣDDT were significantly higher in the samples from the Yenisey Gulf in the Russian Arctic, Svalbard, and East Greenland than in west Greenland or the Canadian Arctic. ΣPCB{sub}10 and ΣDDT in Yenisey Gulf samples were 8× and 6× higher, respectively, than the average in levels from four Canadian locations. ΣPCB{sub}10 and ΣDDT means declined significantly with increasing westerly longitude (r{sup}2 = 0.75 and 0.73, respectively). ΣHCH levels for sites in the Canadian Arctic were significantly higher than those from west Greenland (Qeqertarsuaq), east Greenland (Ittoqqortoormiit), and Svalbard and increased significantly from east to west. The geographical trend ΣHCH is in general agreement with observed trends of HCH in seawater where higher levels have been found in the Canadian Arctic. Higher proportions of more recalcitrant hexa- and pentachloro-PCB congeners were observed in seal blubber samples in the European/Russian Arctic. The continued use of PCBs in electrical equipment and other applications in Russia is a likely source of the more highly chlorinated congeners.
展开▼