Reaction of N-(Trimethylsilyl)MthylCarbodimides With Bifunctional Nucleophiles

摘要

We previously reported the first synthesis of thermally stable (trimethylsilyl)methyl azide and developed a convenient one-pot route for (trimethylsilyl)methyl-substituted isocyanate, isothio-cyanate, carbodiimides, and ketenimine using the iminophosphorane generated from the azide.