Nanocomposite Electrolytes with Fumed Silica and Hectorite Clay network: Passive versus Active Fillers

摘要

The use of nanocomposites constitutes a versatile and robust approach in the development of novel electrolytes with tailored electrochemical and mechanical characteristics. In this study, we examine the morphology, rheology, and ion-transport properties of two types of nanocompoite electrolyte gels, one consisting of branched silica nanoparticles and the other composed of hectorite clay. In the first system with hydrophobic (fumed) silica, oligomers of poly (ethylene oxide) (PEO), and lithium salt, the silica acts as a passive filler ad does not participate in ion transport. The electrochemical properties are controlled by the salt-PEO electrolyte, allowing for ionic conductivities greater than 10~(-3) S cm~(-1) at ambient temperature. At sufficiently high concentrations. the silica forms an elastic gel possessing a large open network structure that provides for unimpeded ion mobility. In the second system composed of lithium-exchanged hecorite filler, the nanoscale platelets serve as the anion. This active filler yields ionic conductivities in excess of 10~(-4) S cm~(-1) and lithium transference numbers approaching unity. Silmilar to fumed silica, the hectorite clay also forms an elastic gel network. However, the morphologies of the two systems are distinctively different both in terms of network structure and characteristic length scale. these morphological differences manifest themselves in different rheological responses with regard to gel modulus and yield stress.