AbstractQuantitative studies on the electrophoretic deposition of a polyimide polymer were carried out over the voltage range 25–100 V dc. Deposition yield was related to voltage, time, and coulombs and was found to obey Faraday's laws of electrolysis. Equations relating yield to voltage and coulombs were obtained from the plotted data. Results of coulombic studies indicate that the effective equivalent weight of the polymeric species being deposited is between 6800 and 7500 (i.e., amount deposited per faraday). The coulombic yield is 75 mg per coulomb. Information and speculation on the size and composition of the electroactive species are presente
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机译:摘要在25–100 V dc电压范围内对聚酰亚胺聚合物的电泳沉积进行了定量研究。沉积产率与电压、时间和库仑有关,并被发现符合法拉第电解定律。从绘制的数据中获得了与电压和库仑相关的方程。库仑研究结果表明,沉积的聚合物物质的有效当量在6800至7500之间(即每法拉第沉积量)。库仑产率为 75 mg/库仑。提供了有关电活性物质的大小和组成的信息和推测
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