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Steam-pyrolysis activation of wood char for superior odorant removal

机译:蒸汽热解活化木炭,去除异味剂

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摘要

A pre-charred, wood-based carbonaceous precursor was activated using a two-step process (steam-pyrolysis activation) to investigate the potential for optimizing an activation protocol for the production of powdered activated carbon (PAC) tailored to effectively remove the taste- and odor-causing compound 2-methylisoborneol (MIB). Activation temperature, activation time, and steam-to-carbon ratio were the activation parameters modified to find the best operating conditions. The success of the tailored PACs was judged on performance in batch experiments, which were designed to simulate actual water treatment plant conditions and used natural water spiked with ~(14)C-MIB. Activation temperature had the greatest impact on PAC performance, with 1123 K providing the best operating point. The pore size distribution data revealed a strong correlation between an increase in mesoporosity and MIB removal in the raw waters. In addition, the tailored PAC with the optimized activation protocol outperformed existing commercially available PAC, indicating the plausibility of tailoring activation protocols for superior MIB removal from natural waters.
机译:使用两步法(蒸汽热解活化)活化预烧焦的木质碳质前体,以研究优化粉末活性炭 (PAC) 生产活化方案的潜力,该方案旨在有效去除引起味道和气味的化合物 2-甲基异龙脑 (MIB)。活化温度、活化时间和蒸汽碳比是修改活化参数以找到最佳操作条件。定制PAC的成功是根据批量实验的性能来判断的,这些实验旨在模拟实际的水处理厂条件,并使用添加了~(14)C-MIB的天然水。活化温度对 PAC 性能的影响最大,1123 K 提供最佳工作点。孔径分布数据显示,原水中介孔度的增加与MIB去除之间存在很强的相关性。此外,具有优化激活方案的定制 PAC 优于现有的市售 PAC,这表明定制激活方案以从天然水中去除 MIB 的合理性。

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