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Morphological studies of blends containing liquid crystalline polymers with poly(ethylene terephthalate)

机译:含有液晶聚合物与聚对苯二甲酸乙二醇酯的共混物的形态学研究

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AbstractThe investigation involved the structure–property behavior of extruded cast films prepared from blends of thermotropic liquid crystalline copolyesters with poly(ethylene terephthalate) (PET). Data were obtained which showed not only the temperature dependence of the moduli and stress–strain behavior but also the orientation effects that must be prevalent in order to explain the differences between the moduli measured parallel and perpendicular to the extrusion direction. Only at high liquid crystal polymer (LCP) composition is the modulus particularly increased. The modulus enhancement with lower LCP content and utilization of process variables are discussed with respect to the induced morphological textures and nature of the process equipment. Specifically, the process variable extruder gear pump speed did not enhance Young's modulus at the same LCP content as extensively as did the process variable of extruder screw sp
机译:摘要研究了热向液晶共聚酯与聚对苯二甲酸乙二醇酯(PET)共混物制备的挤出流延膜的结构-性能。获得的数据不仅显示了模量和应力-应变行为的温度依赖性,还显示了必须普遍存在的取向效应,以解释平行于挤压方向和垂直于挤压方向测量的模量之间的差异。只有在高液晶聚合物(LCP)成分下,模量才会特别增加。讨论了低LCP含量下的模量增强和工艺变量的利用,以及工艺设备的诱导形态织构和性质。具体而言,在相同的LCP含量下,工艺可变挤出机齿轮泵转速并没有像挤出机螺杆sp的工艺变量那样广泛地提高杨氏模量

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