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Poly(methyl methacrylate) as incorporation medium for spent ion‐exchange resin. II. Simulated resin

机译:聚甲基丙烯酸甲酯作为废离子交换树脂的掺入介质。二、模拟树脂

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AbstractThe incorporation and final containment of spent ion‐exchange resins into poly(methyl methacrylate) (PMMA) was investigated in the present study. Test blocks of PMMA with 50 incorporated inactive resin were subjected to radiation doses of 105–107rad at a dose rate of 50 rad/s. The high radiation doses impaired the mechanical properties of the final products. Both compressive strength and hardness decreased with increasing the particle size of the ion‐exchange resin. DTA diagrams showed the thermal instability of the final solidification product at about 400°C. Leaching experiments on incorporated blocks of active resins labelled with Cs‐137 and Ce‐144 showed that cesium activity was more easily released in leachant solutions than was cerium activity. Cumulative leaching rates for both Cs and Ce were lower in deionized water than in undergroud water. The mechanical, thermal, and leaching data obtained illustrate the suitability of PMMA for immobilization of spent ion‐exchange resins with low speci
机译:摘要 本研究探讨了用过的离子交换树脂在聚甲基丙烯酸甲酯(PMMA)中的掺入和最终封装。掺入 50% 非活性树脂的 PMMA 试块以 50 rad/s 的剂量率承受 105-107rad 的辐射剂量。高辐射剂量损害了最终产品的机械性能。抗压强度和硬度均随着离子交换树脂粒径的增加而降低。DTA图显示了最终凝固产物在约400°C下的热不稳定性。 对用Cs-137和Ce-144标记的活性树脂的掺入块进行浸出实验表明,铯活性在浸出溶液中比铈活性更容易释放。去离子水中Cs和Ce的累积浸出速率均低于潜温水。获得的机械、热和浸出数据说明了PMMA适用于固定低规格的废离子交换树脂。

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