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首页> 外文期刊>Metallurgist >CHLORINATION ROASTING OF OXIDIZED COMPONENT OBTAINED FROM DROSS AT A TEMPERATURE OF 1000° C
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CHLORINATION ROASTING OF OXIDIZED COMPONENT OBTAINED FROM DROSS AT A TEMPERATURE OF 1000° C

机译:从渣滓中得到的氧化成分在1000°C的温度下进行氯化焙烧

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Work is devoted to solution of the problem of processing dross obtained as a result of hot galvanizing of products, in particular, waste-free utilization of its oxidized component by chlorination firing using cheap chlorine-containing CaCl_2 and NH_4Cl reagents. Results of chlorination roasting of the dross oxidized component together with CaCl_2 and NH_4Cl at a 1000°C are presented. The effect of CaCl_2 and NH_4Cl consumption on lead and iron sublimation from the dross oxidized component in the form of chlorides is studied. It is found that use of CaCl_2 with a consumption equal to 6 of the weight of the oxidized component provides thorough purification of the starting material from Pb, Cu, Ni, Cd. Maximum reduction of the iron content is not possible. It is shown that use of NH_4Cl with a consumption of 15 of the weight of the oxidized component provides thorough removal of impurity metals and metallic zinc from the source material. It is found that with a firing temperature of 1000°C thorough sublimation of impurities is achieved, which ensures production of pure zinc oxide, suitable for use as a mineral additive in animal and bird feed. The content of metal impurities in the resulting zinc oxide is, wt.: Pb 0.02, Fe 0.08, Ni 0.02, Cu 0.008, Cd 0.001. Optimum firing parameters are established: T = 1000°C, duration 60 min, air flow 0.1 liter/min, CaCl_2 consumption 6, and NH_4Cl 15 of the weight of the oxidized component.
机译:致力于解决因产品热镀锌而产生的渣滓处理问题,特别是通过使用廉价的含氯CaCl_2和NH_4Cl试剂进行氯化烧制,无废物地利用其氧化成分。给出了渣滓氧化组分在1000°C下进行氯化焙烧和CaCl_2和NH_4Cl的结果。研究了CaCl_2和NH_4Cl消耗对氯化物形式的渣滓氧化组分铅和铁升华的影响。研究发现,使用消耗量等于氧化组分重量6%的CaCl_2,可以彻底纯化铅、铜、镍、镉的起始材料,但铁含量不可能最大化。结果表明,使用消耗量为氧化成分重量15%的NH_4Cl可以彻底去除源材料中的杂质金属和金属锌。研究发现,在1000°C的烧制温度下,杂质得到彻底升华,保证了纯氧化锌的生产,适合用作动物和禽类饲料中的矿物添加剂。所得氧化锌中金属杂质的含量为:铅0.02、铁0.08、镍0.02、铜0.008、镉0.001。建立了最佳烧成参数:T = 1000°C,持续时间 60 分钟,空气流量 0.1 升/分钟,CaCl_2消耗量 6%,NH_4Cl氧化成分重量的 15%。

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