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Mechanical properties of 3D printed micro-nano rice husk/polylactic acid filaments

机译:3D打印微纳米稻壳/聚乳酸长丝的力学性能

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摘要

In this study, micro-nano rice husks (MNRH) fibers are compounded in polylactic acid (PLA) to produce 3D-printed filaments by using melt blending method, and some properties of the printed samples of different surface treatment processes are measured. Two silane coupling agents of KH550 and KH570 are severally used on MNRH and PLA to mitigate the surface quality deficiencies for an intimate interfacial bond. Microstructural analysis shows that the MNRH fibers of the composites treated by silane coupling agent have a better dispersing performance. Fourier transform infrared illustrates that the KH550 and KH570 are successfully grafted onto PLA and MNRH fibers. Thermogravimetric analysis (TGA/DSC) suggests that the thermostability and crystallinity of the composites treated by silane coupling agents are enhanced. Water absorption experiments shows that the water resistance of the composites is greatly increased by KH550 and KH570. In comparison with pure PLA, the tensile strength, tensile modulus, bending strength and bending modulus of the 6 wt. MNRH/PLA composites that treated by KH550 and KH570 are enhanced by 83, 98, 54, and 61, respectively. The composites treated by KH550 and KH570 demonstrates the best performance, suggesting that they have great potential for use as an environmentally friendly alternative material in automotive interiors.
机译:本研究采用熔融共混法将微纳米稻壳(MNRH)纤维与聚乳酸(PLA)复合制备3D打印长丝,并测量了不同表面处理工艺打印样品的一些性能。KH550 和 KH570 两种硅烷偶联剂分别用于 MNRH 和 PLA,以减轻表面质量缺陷,从而实现紧密的界面粘合。微观结构分析表明,硅烷偶联剂处理的复合材料的MNRH纤维具有较好的分散性能。傅里叶变换红外表明,KH550和KH570已成功接枝到PLA和MNRH纤维上。热重分析(TGA/DSC)表明,硅烷偶联剂处理的复合材料的热稳定性和结晶度均有提高。吸水率实验表明,KH550和KH570大大提高了复合材料的耐水性。与纯PLA相比,KH550和KH570处理的6 wt.% MNRH/PLA复合材料的拉伸强度、拉伸模量、弯曲强度和弯曲模量分别提高了83%、98%、54%和61%。经过KH550和KH570处理的复合材料表现出最佳性能,表明它们作为汽车内饰的环保替代材料具有巨大的潜力。

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