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Cure kinetics and mechanical properties of carbonized chicken feather reinforced styrene butadiene rubber composites

机译:炭化鸡毛增强丁苯橡胶复合材料的固化动力学和力学性能

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摘要

Abstract Polymers are part and parcel of our life and society due to the immense applications resulting from their unique properties. High performing products based on bio feed stocks have gained special attention compared to non‐renewable resources. In the present research work, carbon black (CCF) prepared from waste chicken feathers has been used as reinforcement in styrene butadiene rubber (SBR). Cure kinetics of SBR‐CCF composites and their mechanical properties have been evaluated with respect to loading of filler and concentration of dicumyl peroxide crosslinking agent. The cure reaction of all compounds obeys first order kinetics and the rate constants increase with filler loading as well as temperature. A decrease in energy of activation of cure has been noted with increase of loading of CCF filler, which assists for an increase in the rate of production of articles using the filled SBR compounds. The improvement in tensile properties with CCF has been supported by the fractography of the composites and by the crosslink density values obtained using equilibrium swelling method. The performance of the developed composites points to their applications in the area of car‐tire industry, tread rubber sector and structural applications such as drive and shaft couplings.
机译:摘要 聚合物因其独特的性能而具有广泛的应用,是我们生活和社会的重要组成部分。与不可再生资源相比,基于生物原料的高性能产品受到特别关注。在本研究工作中,由废鸡毛制备的炭黑(CCF)已被用作丁苯橡胶(SBR)的补强材料。SBR-CCF复合材料的固化动力学及其机械性能已通过填料的负载和过氧化二异丙苯交联剂的浓度进行了评估。所有化合物的固化反应均遵循一级动力学,速率常数随填料负载量和温度的增加而增加。已经注意到,随着CCF填料的负载量的增加,固化活化的能量降低,这有助于提高使用填充的SBR化合物的制品的生产率。CCF拉伸性能的改善得到了复合材料的分形成像和使用平衡溶胀法获得的交联密度值的支持。所开发的复合材料的性能表明它们在汽车轮胎工业、胎面橡胶行业以及驱动和联轴器等结构应用中的应用。

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