Microwave sintering of high-performance BaZr_(0.1)Ce_(0.7)Y_(0.1)Yb_(0.1)O_(3-δ) (BZCYYb) electrolytes for intermediate-temperature solid oxide fuel cells

摘要

As a promising electrolyte material for solid oxide fuel cells (SOFCs), BaZr_(0.1)Ce_(0.7)Y_(0.1)Yb_(0.1)O_(3-δ) (BZCYYb) often surfers from its high sintering temperature, which causes Ba evaporation and sluggish grain growth, thus reducing the electrical conductivity. In this work, densified BZCYYb electrolytes were fabricated at temperatures as low as 1400 ℃ using the microwave sintering technique. Comparing with the conventional sintered ones, a temperature decrease of 150 ℃ is achieved. The Ba evaporation is effectively suppressed, and large grain sizes of ~4 μm are obtained. The total conductivity for microwave sintered symmetric cell measured in wet air at 700 ℃ is 3.8 × 10~(-2) S cm~(-1), benefiting from both enhanced bulk conductivities by 1-2 times and grain boundary conductivities by 50 times. With the microwave sintered BZCYYb as electrolyte, an anode-supported cell reaches a maximum power density of 0.64 W cm~(-2) at 700 ℃.