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Optimization of the Electrode Formation Mechanism for Crystalline Silicon Heterojunction Solar Cells

机译:晶体硅异质结太阳能电池电极形成机理的优化

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摘要

The screen-printing process for making good contact of electrodes with the top layer of solar cells is crucial for enhancing the electrical properties of a solar cell. This paper reports the experimental approach adopted for the process of electrode formation and the resulting shape of electrodes in silicon-based heterojunction (SHJ) solar cells. It was observed that good contact between electrodes and the top transparent conductive oxide (TCO) layer strongly depends on the squeegee pressure, curing temperature, and curing time. By optimizing the squeegee pressure at 0.350 MPa, snap-off distance of 1.4 mm, squeegee speed of 80 mm sec(-1), curing temperature of 180 degrees C, and curing time of 30 min, respectively for which the height to width ratio (aspect ratio) of the fabricated electrodes was achieved around 0.66. The results have been verified through 3D laser profiler, field emission scanning electron microscopy (FE-SEM), transfer length method (TLM), and Light current-voltage (LIV) measurements. The SHJ solar cells were fabricated using an optimized condition and successfully achieved splendid properties of short circuit current density (J(sc)), open circuit voltage (V-oc), fill factor (FF), and efficiency (eta) up to 40.57 mA cm(-2), 723 mV, 81.03, and 23.79, respectively.
机译:使电极与太阳能电池顶层良好接触的丝网印刷工艺对于提高太阳能电池的电性能至关重要。本文报道了硅基异质结(SHJ)太阳能电池中电极形成过程的实验方法以及由此产生的电极形状。据观察,电极与顶部透明导电氧化物(TCO)层之间的良好接触在很大程度上取决于刮刀压力、固化温度和固化时间。通过优化0.350 MPa的刮刀压力、1.4 mm的折断距离、80 mm sec(-1)、180°C的固化温度和30 min的固化时间,制备电极的长宽比(长宽比)分别达到0.66左右。通过三维激光轮廓仪、场发射扫描电子显微镜(FE-SEM)、传输长度法(TLM)和光电流-电压(LIV)测量验证了结果。采用优化条件制备的SHJ太阳能电池,成功实现了短路电流密度(J(sc))、开路电压(V-oc)、填充因子(FF)和效率(eta)的出色性能,分别高达40.57 mA cm(-2)、723 mV、81.03%和23.79%。

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