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A Dual-Function Carbon Quantum Dot Fluorescent Probe for the Detection of Fe3+ and Sunset Yellow

机译:一种用于检测Fe3+和日落黄的双功能碳量子点荧光探针

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摘要

There are few researches on the application of multifunctional carbon quantum dots (CQDs) in analysis and detection. In this study, carbon quantum dots (CQDs) with dual-function detection were synthesized by the one-step hydrothermal method with citric acid as the carbon source and o-phenylendiamine as the nitrogen source to detect Fe3+ and sunset yellow. The morphology of the prepared CQDs and the surface functional groups were characterized using TEM, FTIR, XPS, UV-Vis spectroscopy, and fluorescence spectrophotometer. The results show that the morphology of CQDs is nearly spherical and well dispersed, with a particle size range of 1.24 similar to 6 nm and the average particle size was 3.23 nm. The surface of the CQDs has hydrophilic groups, such as OH, -COOH and -NH2. CQDs exhibited good acid and alkali resistance, salt resistance, and photobleaching resistance under different conditions. The detection limits of CQDs for Fe3+ and sunset yellow were 1.52 mu M and 0.812 mu M, respectively. The recoveries of actual samples were 96.65 similar to 104.85 and 95.4 similar to 104.55 , with relative standard deviations (RSDs) of less than 6 . Therefore, CQDs can be employed as dual-function fluorescent probes in the practical detection of samples and have promising application prospects.
机译:关于多功能碳量子点(CQDs)在分析和检测中的应用的研究较少。本研究以柠檬酸为碳源,邻苯二胺为氮源,采用一步水热法合成了具有双重功能检测的碳量子点(CQDs),用于检测Fe3+和日落黄。采用TEM、FTIR、XPS、紫外-可见分光光度计和荧光分光光度计对所制备的CQDs的形貌和表面官能团进行了表征。结果表明:CQDs的形貌近球形且分散性好,粒径范围为1.24,与6 nm相似,平均粒径为3.23 nm;CQDs表面具有亲水基团,如OH、-COOH和-NH2。CQDs在不同条件下均表现出良好的耐酸碱性、耐盐性和耐光漂白性。CQDs对Fe3+和日落黄的检出限分别为1.52 μ M和0.812 μ M。实际样品的回收率为96.65%(104.85%)和95.4%(104.55%),相对标准偏差(RSD)小于6%。因此,CQDs可作为双功能荧光探针应用于样品的实际检测,具有广阔的应用前景。

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