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Microstructure and mechanical properties of Mg-GdH2 composite prepared by internal hydrogenation

机译:内加氢制备Mg-GdH2复合材料的微观结构与力学性能

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摘要

In this study, Mg-GdH2 composite was prepared by internal hydrogenation treatment (IHT) of Mg-5Gd (wt) alloy at 300 and 325 degrees C for 36 and 48 h under hydrogen pressure of 0.34 MPa. Phase transformations during the hydrogenation process and mechanical properties of the composites were investigated. During the IHT, Gd in the alpha-Mg matrix reacted with hydrogen and formed GdH2 precipitates. The results indicated that Mg metal matrix composite reinforced with uniformly dispersed GdH2 hydride particles could be obtained after IHT. The strength of the Mg-GdH2 composite was inferior to that of the Mg-5Gd alloy in which Gd is dissolved in alpha-Mg solid solution. This implied that the formation of GdH2 precipitates did not result in further strengthening of the as-cast alloy. Analysis of strengthening mechanisms indicated that the strengthening effects brought by GdH2 precipitates were not able to compensate the loss of solid solution strengthening effect due to Gd dissolved in alpha-Mg. The decrease in strength was accompanied with the increase in ductility, which was due to the grain growth in Mg matrix and annihilation of defects. From these results, the potential of IHT to improve the strength of Mg-RE alloys is inferred, and recommendations for future studies are presented.
机译:本研究以Mg-5Gd(wt%)合金在300和325°C、0.34 MPa的氢气压力下,历时36和48 h,制备了Mg-GdH2复合材料。研究了加氢过程中的相变和复合材料的力学性能。在IHT过程中,α-Mg基质中的Gd与氢反应并形成GdH2沉淀物。结果表明,IHT后可以得到均匀分散的GdH2氢化物颗粒增强的Mg金属基复合材料。Mg-GdH2复合材料的强度不如Mg-5Gd合金,其中Gd溶解在α-Mg固溶体中。这意味着GdH2沉淀物的形成不会导致铸时合金的进一步强化。强化机理分析表明,GdH2析出物带来的强化效应无法补偿Gd溶解在α-Mg中的固溶强化效果的损失。强度的降低伴随着延展性的增加,这是由于Mg基体中的晶粒生长和缺陷的消除。从这些结果中,推断出IHT在提高Mg-RE合金强度方面的潜力,并提出了对未来研究的建议。

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