A dynamic supercritical carbon dioxide foaming method for fabricating wrinkled surface to enhance triboelectric nanogenerator performance

摘要

Triboelectric nanogenerator (TENG) is a promising energy harvester to overcome the energy depletion issue. The surface structure has been considered as an effective way to enhance the triboelectric performance. Herein, a dynamic supercritical carbon dioxide (scCO(2)) foaming method, which introduced a scCO(2) flow field during scCO(2) saturation, was proposed to fabricate thermoplastic polyurethane (TPU) foams with surface wrinkly structures. The size of the surface wrinkles could be regulated in the range of 1.8-10 mu m by varying the foaming pressure. The surface wrinkled TPU film with wrinkle wave length of 2.4 mu m demonstrated an excellent enhancement in output voltage (130), current (180), and maximum transfer charge (130) when paired with surface structured polydimethylsiloxane film in a TENG. Due to the excellent durability and flexibility of the composing materials, the developed TENG showed outstanding stability in long-term continuous operation. With a high power density of 0.5 W/m(2) achieved on a 10(7) omega external load, the flexible TENG could be used to charge capacitors, power light-emitting-diodes, and served as a self-powered sensor to detect various human movement behaviors. This work provides a new path for the fabrication of surface wrinkled films for the sustainable development of high performance TENGs.