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Process simulation and optimization of groundnut shell biomass air gasification for hydrogen-enriched syngas production

机译:花生壳生物质空气气化生产富氢合成气的工艺模拟与优化

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摘要

In this study, a detailed steady-state equilibrium simulation model was designed using ASPEN Plus software to analyze and assess the efficiency of the groundnut shell biomass air gasification process. The developed model includes three general stages: biomass drying, pyrolysis, and gasification. The predicted results are quite similar to those found in the literature, which is consistent with simulation results being validated against experimental data. The effect of different operating parameters, like the gasification temperature, gasification pressure, and the equivalence ratio (ER), on the syngas composition and H2/CO ratio is investigated using sensitivity analysis. The findings of the sensitivity analysis revealed that raising the temperature preferred H2 and CO production, whereas increasing the pressure has favored CO2 and CH4 production. Increasing the ER value also boosted CO and CO2 yield. Moreover, in an effort to optimize the amount of H2 generated within the process, the sensitivity analysis was used to evaluate the simultaneous effect of operational parameters on the molar fraction of H2. To maximize H2 as a desired product, the following operating parameters were achieved: gasification temperature of 894 degrees C, gasification pressure of 1 bar, and ER of 0.05, resulting in an H2 molar fraction of 0.64. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:本研究利用ASPEN Plus软件设计了详细的稳态平衡模拟模型,对花生壳生物质空气气化过程的效率进行了分析和评估。开发的模型包括三个一般阶段:生物质干燥、热解和气化。预测结果与文献中的结果非常相似,这与根据实验数据验证的仿真结果一致。采用灵敏度分析研究了气化温度、气化压力和当量比(ER)等不同操作参数对合成气成分和H2/CO比的影响。灵敏度分析结果表明,升高温度有利于H2和CO的产生,而增加压力有利于CO2和CH4的产生。增加 ER 值也提高了 CO 和 CO2 产量。此外,为了优化过程中产生的 H2 量,使用灵敏度分析来评估操作参数对 H2 摩尔分数的同步影响。为了最大限度地将 H2 作为所需产品,实现了以下操作参数:气化温度为 894 摄氏度,气化压力为 1 bar,ER 为 0.05,导致 H2 摩尔分数为 0.64。(c) 2022 Hydrogen Energy Publications LLC.,由爱思唯尔有限公司出版。保留所有权利。

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