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A highly robust, non‐fluorinated, and economical PDMS‐based superhydrophobic flexible surface with repairable and flame‐retardant properties

机译:基于PDMS的高度坚固、无氟且经济的超疏水柔性表面,具有可修复和阻燃性能

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摘要

Abstract Nature‐inspired artificial superhydrophobic surfaces have attracted tremendous attention due to their potential applications in various fields. However, the use of toxic chemicals and expensive nanoparticles with limited durability has restricted the practical applications of these surfaces. Here, we proposed a novel and non‐fluorinated technique to fabricate robust and flexible polydimethylsiloxane (PDMS)‐based superhydrophobic surface. Fabrication involved two simple steps: preparation of superhydrophobic nanoparticles by burning PDMS, and fabrication of flexible superhydrophobic PDMS surface (SPS) by dispersing particles in a solvent containing PDMS solution and curing agent. Effect of PDMS particle content on morphology and wettability was examined and 10 wt. PDMS nanoparticles demonstrated superior superhydrophobicity with a water contact angle of 156° and sliding angle of ~6°. The SPS displayed excellent mechanical robustness in a sandpaper abrasion test and showed no apparent wettability deterioration even when stretched by up to 50. Additionally, surface maintained outstanding superhydrophobicity even after 300 cycles of mechanical deformation. Impressively, damaged surface can restore its superhydrophobicity after removing the damaged layer using sandpaper abrasion and displayed exceptional chemical, thermal, flame‐retardant, and long‐lasting superhydrophobic properties. The work provides an innovative, low‐cost, and environment‐friendly strategy for designing robust and flexible superhydrophobic surfaces that can be used in real‐life applications.
机译:摘要 受自然启发的人造超疏水表面因其在各个领域的潜在应用而受到广泛关注。然而,使用有毒化学品和昂贵的纳米颗粒且耐久性有限,限制了这些表面的实际应用。在这里,我们提出了一种新的无氟技术来制造坚固且柔韧的聚二甲基硅氧烷(PDMS)基超疏水表面。制备涉及两个简单的步骤:通过燃烧PDMS制备超疏水纳米颗粒,以及通过将颗粒分散在含有PDMS溶液和固化剂的溶剂中来制备柔性超疏水PDMS表面(SPS)。研究了PDMS颗粒含量对形貌和润湿性的影响,10 wt.%的PDMS纳米颗粒表现出优异的超疏水性,水接触角为156°,滑动角为~6°。SPS在砂纸磨损测试中表现出优异的机械强度,即使拉伸高达50%,也没有显示出明显的润湿性劣化。此外,即使在300次机械变形循环后,表面仍保持出色的超疏水性。令人印象深刻的是,在使用砂纸磨损去除受损层后,受损表面可以恢复其超疏水性,并显示出卓越的化学、热、阻燃和持久的超疏水性能。这项工作提供了一种创新、低成本和环保的策略,用于设计可用于实际应用的坚固而灵活的超疏水表面。

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