Additive manufacturing of flame retardant polyamide 12 with high mechanical properties from regenerated powder

摘要

Purpose - This paper aims to develop flame-retardant (FR) polyamide 12 (PA12) nanocomposite from regenerated powder via selective laser sintering (SLS), an additive manufacturing technique.Design/methodology/approach - First, the morphology, processibility, thermal and mechanical properties of PA12 regenerated powder, consisting of 50 wt new and 50 wt recycled powder, as well as corresponding printed specimens, were evaluated to characterize the effects of previous SLS processing. Second, flame-retardant PA12 was developed by incorporating both single and binary halogen-free flame retardants into the regenerated powder.Findings - It was found that the printed specimens from regenerated powder had much higher tensile and impact properties compared to specimens made from new powder, which is attributed to better particulate fusion and coalescence realized in higher temperature SLS printing. The effect of FRs on thermal, mechanical and flame retardant properties of the PA12 composites/nanocomposites was investigated systematically. It was found that the nanoclay, as a synergist, improved both flame-retardant and mechanical properties of PA12. UL94 standard rating of V-0 was achieved for the printed nanocomposite by incorporating 1 wt nanoclay into 15 wt phosphinates FR. Moreover, on average, the tensile and impact strength of the nanocomposite were increased by 26.13 and 17.09, respectively, in XY, YZ and Z printing orientations as compared to the equivalent flame retardant composite with 20 wt of the phosphinates FR.Originality/value - This paper fulfills the need to develop flame retardant parts via SLS technology with waste feedstock. It also addresses the challenge of developing flame retardant materials without obviously compromising the mechanical properties by making use of the synergistic effect of nanoclay and organic phosphinates.