首页> 外文期刊>KSCE journal of civil engineering >Degradation Mechanisms of Chloride Contaminated Cast-in-Situ Concrete Partially Exposed to Magnesium-Sulfate Combined Environment
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Degradation Mechanisms of Chloride Contaminated Cast-in-Situ Concrete Partially Exposed to Magnesium-Sulfate Combined Environment

机译:部分暴露于镁硫酸盐复合环境的氯化物污染现浇混凝土降解机理

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摘要

Cast-in-situ concrete suffers complicated working conditions in sulfate-rich saline soil areas. Sulfate-magnesium combined attack can be encountered in heavy saline or salty lake areas. This study investigated the degradation process and corresponding mechanisms of cast-in-situ concrete, contaminated by chlorides, partially exposed to sulfate-magnesium combined corrosive environments. Concrete samples were cast and partially immersed in the pre-prepared distilled water, sulfate or sulfate-magnesium mixed solutions for 12 months. Physical and mechanical properties of concrete samples were continuously measured and recorded during the immersion. Sulfate concentration in different depths were measured by chemical titration. SEM, XRD, TC/DTG tests were conducted to analyze the microstructural and mineral property changes after corrosion for concrete suffered different corrosion conditions. Results show that partially immersed concrete encounters both chemical and physical degradation induced by corrosive sources. Concrete contaminated by chlorides obviously shows weaker resistance against sulfate attack and the strength development is also negatively affected. Magnesium in the environments reduces the early strength of partially immersed cast-in-situ concrete while enhancing the sulfate resistance ability in the later corrosion stage. Magnesium limits the negative effect of contaminated chlorides on the partially immersed cast-in-situ concrete. Performance of cast-in-situ concrete is different from precast concrete when encountering different corrosive sources, and thus more attention should be paid on the degradation of cast-in-situ concrete structures induce by aggressive environments.
机译:现浇混凝土在富含硫酸盐的盐渍土地区具有复杂的工作条件。在重盐或咸湖区可遇到硫酸盐-镁联合攻击。本研究探讨了现浇混凝土在部分硫酸盐-镁复合腐蚀环境中被氯化物污染的降解过程及机理。将混凝土样品浇筑并部分浸入预先制备的蒸馏水、硫酸盐或硫酸盐-镁混合溶液中 12 个月。在浸泡过程中连续测量和记录混凝土样品的物理和机械性能。通过化学滴定法测定不同深度的硫酸盐浓度。采用SEM、XRD、TC/DTG等试验,分析了不同腐蚀条件下混凝土腐蚀后的微观结构和矿物性能变化。结果表明:部分浸入混凝土在腐蚀源的化学降解和物理降解中均存在。被氯化物污染的混凝土对硫酸盐侵蚀的抵抗力明显较弱,强度发展也受到负面影响。环境中的镁降低了部分浸没式现浇混凝土的早期强度,同时增强了后期腐蚀阶段的抗硫酸盐能力。镁限制了受污染的氯化物对部分浸泡的现浇混凝土的负面影响。现浇混凝土在遇到不同腐蚀源时的性能与预制混凝土不同,因此应更加关注侵蚀性环境对现浇混凝土结构的降解。

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