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Effect of natural biomass fillers on the stability, degradability, and elasticity of crop straws liquefied polyols-based polyurethane foams

机译:天然生物质填料对农作物秸秆液化多元醇基聚氨酯泡沫稳定性、降解性和弹性的影响

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摘要

Oilseed rape straw (OS), rice straw (RS), wheat straw (WS), and corn stover (CS) particles were used to reinforce bio-polyols based polyurethane (PU) foams. The influence of crop straws (XS) fillers on the stability in water, degradability in soil, thermal stability, and elasticity of foams were investigated. The incorporation of OS and CS particles in the PU matrix increased the stability of reinforced foams in water, while the addition of WS and RS particles made foams lower stability in water. PU foams reinforced by XS particles displayed mass reductions up to 53.8 after burying in soil for 250 days. The reinforced foams were more stable under heating but the enhancement of thermal stability trended to disappear after water immersion or soil burying. The reinforced foams showed better elasticity that incorporations of OS and CS made PU foams higher height recovery percentage, while RS and WS made the recovery percentage decline firstly and then enhance during three times compressions. All these four XS particles are suitable to modify bio-based PU foams, especially OS and CS particles appear to be more outstanding in preparing foams with higher stability in water, degradability in soil, thermal stability, and elasticity than RS and WS particles.
机译:油菜秸秆(OS)、水稻秸秆(RS)、小麦秸秆(WS)和玉米秸秆(CS)颗粒用于增强生物多元醇基聚氨酯(PU)泡沫。研究了作物秸秆填料对水稳定性、土壤降解性、热稳定性和泡沫弹性的影响。在PU基体中掺入OS和CS颗粒可提高增强泡沫在水中的稳定性,而WS和RS颗粒的加入会降低泡沫在水中的稳定性。XS颗粒增强的聚氨酯泡沫在土壤中埋藏250 d后,质量减少高达53.8%。增强泡沫在加热下更稳定,但水浸或埋土后热稳定性的增强趋势消失。增强泡沫表现出更好的弹性,OS和CS的掺入使PU泡沫的高度回收率更高,而RS和WS使回收率先下降后增强。这4种XS颗粒均适用于生物基聚氨酯泡沫的改性,特别是OS和CS颗粒在制备泡沫方面比RS和WS颗粒具有更高的水稳定性、土壤降解性、热稳定性和弹性。

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