Development of NiO/Co_3O_4 nanohybrids catalyst with oxygen vacancy for oxygen evolution reaction enhancement in alkaline solution

摘要

The oxygen evolution reaction (OER) is a significant reaction in water splitting and energy conversion. However, high price and sluggish kinetics catalysts prevent commercial applications. Generally, noble metals (e.g., iridium and ruthenium), which are expensive and unstable, have been used as catalysts for OER because of their high electrocatalytic activity. In this study, we report a high-performance OER catalyst with oxygen vacancies comprising NiO/Cosub3/subOsub4/sub nanohybrids. For OER, the NiO/Cosub3/subOsub4/sub heterostructure show good electrocatalytic performance with a low overpotential of 330 mV. This is higher than those of NiO, Cosub3/subOsub4/sub, and benchmark IrO2 candidates at current density of 10 mA cm(-2). Furthermore, the NiO/Cosub3/subOsub4/sub nanohybrids show long-term electrochemical stability for 10 h. The present research results show that NiO/Cosub3/subOsub4/sub heterostructure is an excellent electrocatalyst for OER.commentSuperscript/Subscript Available/comment