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Functional Coatings made by Brazing

机译:钎焊功能涂层

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In principle, coatings made by brazing is a process variant of brazing which can be classified as high-temperature brazing. It is a thermal process which is carried out either without flux in a vacuum or under inert gas with tapes/slurries/pastes/powders with a liquidus temperature generally above 900℃. In this process, no components are firmly connected to each other but brazeable materials are applied which, after the heat treatment process, produce a metallic, material-tight coating. The most commonly used filler matrix materials are nickel-based ones, cobalt, iron, copper-based ones or corresponding alloys. Hard materials are mixed in depending on the coating function. Carbides, silicides, borides, oxides, diamonds, CBn or hard material mixtures can be used as hard materials. Common industrial used hard materials are WC, CrC or NbC. Hard material proportions in the coating can be up to 80 Vol.. Actual developments show contents up to 90 Vol. and more. Depending on the application, layer matrix hardnesses are flexibly adjustable from 20-30 HRC to 62-65 HRC. The coating produced can therefore perform various functions. For this reason, they are also called functional coatings. For example, hard material particles introduced into the matrix can be firmly brazed onto the surface of the component and thus take on a wear protection or gripping function. Alternatively, worn components such as moulds or turbine blades can be recontoured by brazing suitable materials as tapes or slurries into the wear areas and then reworking them. The coatings are very dense and crack-free and are therefore also very suitable for corrosion protection, even at high temperatures. In contrast to deposit welding, the deposit-brazed coatings are relatively smooth and often do not need to be reworked or ground. The strength of high-temperature brazed hard material coatings can reach the strength of the base materials. This results in a highly stressable layered composite. 2D and 3D geometries can be coated both internally and externally. Coating thicknesses are usually ranging from 1.0 up to 4.0 mm. Minimum layer thicknesses of 0.05-0.1 mm up to 10 mm and more can be achieved. Recent developments also show the possibility of locally brazing on applied tapes or suspensions using laser energy without having to heat the entire component. By selecting appropriate morphologies of the starting powders for braze matrix materials and hard materials, the coating system can be specifically optimised and adapted for the respective application. In addition, work is being carried out on systems in which "signaling elements" are incorporated into the coating in order to record the condition of a surface during operation. For example, forces, wear or temperature. The lecture gives an overview of selected processes, materials and applications and an outlook on new developments.
机译:原则上,钎焊制成的涂层是钎焊的一种工艺变体,可归类为高温钎焊。它是一种热过程,在真空中或在惰性气体下使用液相线温度通常高于 900°C 的胶带/浆料/糊状物/粉末进行无助焊剂。在这个过程中,没有组件彼此牢固地连接,而是应用了可钎焊材料,在热处理过程之后,会产生金属、材料密封的涂层。最常用的填充基体材料是镍基、钴基、铁基、铜基或相应的合金。根据涂层功能混合硬质材料。碳化物、硅化物、硼化物、氧化物、金刚石、CBn或硬质材料混合物均可用作硬质材料。常见的工业用硬质材料有WC、CrC或NbC,涂层中的硬质材料比例可达80 Vol.%。实际开发显示内容高达 90 Vol.% 甚至更多。根据应用的不同,层基体硬度可在 20-30 HRC 至 62-65 HRC 之间灵活调节。因此,生产的涂层可以执行各种功能。因此,它们也被称为功能性涂层。例如,引入基体的硬质材料颗粒可以牢固地钎焊到部件表面,从而具有磨损保护或夹持功能。或者,可以将合适的材料(如胶带或浆料)钎焊到磨损区域,然后对其进行重新加工,从而对模具或涡轮叶片等磨损部件进行重新轮廓加工。涂层非常致密且无裂纹,因此即使在高温下也非常适合防腐蚀。与沉积焊接相比,沉积钎焊涂层相对光滑,通常不需要返工或研磨。高温钎焊硬质材料涂层的强度可以达到基材的强度。这导致了高应力的层状复合材料。2D 和 3D 几何形状可以在内部和外部进行涂层。涂层厚度通常在 1.0 到 4.0 毫米之间。最小层厚可达0.05-0.1毫米至10毫米以上。最近的发展还表明,可以使用激光能量在应用的胶带或悬架上进行局部钎焊,而无需加热整个部件。通过为钎焊基体材料和硬质材料选择合适的起始粉末形态,可以专门优化涂层系统并适应各自的应用。此外,正在对将“信号元件”纳入涂层的系统进行研究,以便在操作过程中记录表面状况。例如,力、磨损或温度。该讲座概述了选定的工艺、材料和应用,并展望了新的发展。

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