Field leaching study-Inverse estimation of degradation and sorption parameters for a mobile soil metabolite and its pesticide parent

摘要

Pesticide concentration measurements from field studies under real-world conditions can improve the derivation of more representative modelling input parameters for the exposure assessment of agrochemicals in the authorization process of plant protection products. The pertinent guidance documents foresee the application of inverse modelling approaches in combination with environmental fate and transport models to estimate e.g., soil dissipation rates that are solely based on microbial degradation and are not lumped with contributions from other dissipation processes such as leaching, plant uptake, volatilization and photodegradation. Field leaching studies can be used to estimate both degradation and sorption of chemicals in the soil matrix. In this study, inverse modelling of environmental fate parameters is presented based on solute concentrations from a field leaching study sampling pore water from five different depths down to 1.5 m. The leaching model PEARL and the universal optimization tool PEST were coupled, and sorption and degradation of the fungicide fluopicolide and its soil metabolite BAM (2,6-dichlorobenzamide) were quantified. Soil degradation half-lives were not different from results obtained in regular field degradation studies sampling residues in the total soil matrix (236 d vs. 158 d for fluopicolide and 53 d vs. 45 d for BAM); whereas a sorption increase with time (time-dependent sorption) was observed for the parent compound. This work aims at pointing out the feasibility to include field leaching studies with measurements at different soil depths in regulatory exposure assessment, since a statistically significant derivation of degradation and sorption parameters is presented, along with low uncertainties in the estimated parameter values of +/- 10%.