Preparation, microstructures, and mechanical properties of directionally solidified Al2O3/Lu3Al5O12 eutectic ceramics

摘要

Al2O3/Lu3Al5O12 (LuAG) directionally solidified eutectic (DSE) ceramics with two solidification rates were prepared utilizing optical floating zone (OFZ) technique. The microstructures (eutectic morphology, preferred growth direction and interface orientation) of Al2O3/LuAG were characterized, and the mechanical properties (Vickers hardness and fracture toughness) were compared with those of Al2O3/REAG (RE = Y, Er, and Yb). Results show that Al2O3/LuAG with solidification rate of 30 mm/h has established preferred growth direction in both Al2O3 and LuAG phases with cellular eutectic structures. While Al2O3/LuAG with solidification rate of 10 mm/h only shows preferred growth direction in Al2O3 phase and presents degenerate irregular eutectic microstructures. Besides, Al2O3/LuAG exhibits higher hardness compared with Al2O3/REAG (RE = Y, Er, and Yb). In addition, a special attention is focused on the relations among rare earth ionic radius, eutectic microstructures, and mechanical properties of these DSE ceramics. It is demonstrated that a smaller rare earth ionic radius could lead to larger eutectic interspacing as well as higher Vickers hardness of DSE Al2O3/REAG, revealing the possibility and feasibility of microstructure control and mechanical properties optimization for DSE Al2O3/REAG ceramics by tailoring the rare earth elements.