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A Novel Biodegradable Polymer-Based Hybrid Nanocomposites for Flexible Energy Storage Systems

机译:一种新型生物降解聚合物基杂化纳米复合材料在柔性储能系统中的应用

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摘要

A polymer nanocomposite shows a distinctive physicochemical property that cannot be acquired by performing on individual components alone. The polymer nanocomposite has an important research interest due to its optimistic capability for functional applications in many fields. Specifically, polymer nanocomposites (PNCs) have attracted important research attention for solving energy and environmental problems. In the present work, poly-vinyl pyrrolidone (PVP)/polyethylene oxide (PEO)/α-Fe_2O_3 is one of the excellent electrode materials for supercapacitors by reason of its low cost. The device was assembled by using PVP/PEO and PVP/PEO/x wt. of α-Fe_2O_3 polymer nanocomposite as the cathode and activated carbon as the anode. The optimized PVP/PEO/Fe_2O_3 composites are bendable electrode materials that show a high specific capacitance of 76.22 mF cm~(-2) at a current density of 1 A cm"2, express a high-power density of 318.18 W Kg~(-1) at an energy density of 3.77 Wh kg~(-1), and have an everlasting performance. This work shows an immense approach of ASC devices to fabricating flexible polymer nanocomposites for high-performance supercapacitor applications. This simple fabrication method helps us to understand and develop a flexible hybrid supercapacitor application. Flexible solid-state asymmetrical supercapacitors bring about a working potential of 1.8 V and attain an outstanding specific capacitance and energy density.
机译:聚合物纳米复合材料具有独特的物理化学性质,无法单独对单个组分进行处理。聚合物纳米复合材料因其在许多领域的功能应用能力而具有重要的研究兴趣。具体而言,聚合物纳米复合材料(PNCs)在解决能源和环境问题方面备受关注。在目前的工作中,聚乙烯吡咯烷酮(PVP)/聚环氧乙烷(PEO)/α-Fe_2O_3因其成本低廉而成为超级电容器的优良电极材料之一。以PVP/PEO和PVP/PEO/x wt.%的α-Fe_2O_3聚合物纳米复合材料为正极,以活性炭为阳极组装该器件。优化后的PVP/PEO/Fe_2O_3复合材料是可弯曲电极材料,在1 A cm“2的电流密度下表现出76.22 mF cm~(-2)的高比电容,在3.77 Wh kg~(-1)的能量密度下表现出318.18 W Kg~(-1)的高功率密度,并具有持久的性能。这项工作展示了ASC器件为高性能超级电容器应用制造柔性聚合物纳米复合材料的巨大方法。这种简单的制造方法有助于我们理解和开发灵活的混合超级电容器应用。柔性固态非对称超级电容器的工作电位为 1.8 V,并具有出色的比电容和能量密度。

著录项

  • 来源
    《Journal of polymers and the environment》 |2023年第4期|1610-1627|共18页
  • 作者单位

    Department of Physics, Government Arts College (Autonomous), Coimbatore 641 018, India, Department of Physics, Nirmala College for Women (Autonomous), Coimbatore 641 018, India;

    Department of Physics, Karpagam Academy of Higher Education, Tamil Nadu, Coimbatore 641 021, India;

    Department of Physics, School of Advanced Sciences, Kalasalingam Academy of Research and Education, Krishnankoil, Srivilliputhur 626 126, IndiaDepartment of Science and Humanities, Karpagam Academy of Higher Education, Coimbatore, Tamil Nadu 641 021, IndiaCentre for High Computing, CSIR-Central Leather Research Institute, Chennai 600 020, IndiaDepartment of Physics, Government Arts College (Autonomous), Coimbatore 641 018, India;

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  • 原文格式 PDF
  • 正文语种 英语
  • 中图分类
  • 关键词

    PVP; PEO; α-Fe_2O_3; Polymer nanocomposite; Cathode; Asymmetric supercapacitors; Energy storage;

    机译:PVP;专业雇主组织;α-Fe_2O_3;高分子纳米复合材料;阴极;非对称超级电容器;储能;
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