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Pulsating propagation and extinction of hydrogen detonations in ultrafine water sprays

机译:Pulsating propagation and extinction of hydrogen detonations in ultrafine water sprays

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Pulsating detonation and extinction in stoichiometric hydrogen/oxygen/argon gas with water sprays are studied for the first time. Eulerian-Lagrangian method is employed, and the emphasis is laid on characterization of the unsteady phenomena and evolutions of chemical / flow structures in pulsating propagation and extinction. Three detonation propagation modes are found: (1) pulsating propagation, (2) propagation followed by extinction, and (3) immediate extinction. For pulsating detonation, within one cycle, the propagation speeds and the distance between reaction front (RF) and shock front (SF) change periodically. The pulsating phenomenon originates from the interactions between gas dynamics, chemical kinetics, and droplet dynamics inside the induction zone. Multiple pressure waves are emanated from the RF within one cycle, which overtake and intensify the lead SF. An autoigniting spot arises in the shocked gas after the contact surface. The relative locations of SF, RF, shock-frame sonic point, and two-phase contact surface remain unchanged in a pulsating cycle, but their distances have periodic variations. Moreover, detonation extinction is featured by continuously increased distance between the RF and SF and quickly reduced pressure peaks, temperature, and combustion heat release. The decoupling of RF and SF leads to significantly increasing chemical timescale of the shocked mixture. The hydrodynamic structure also changes considerably when detonation extinction occurs. Moreover, the predicted map of detonation propagation and extinction illustrates that the critical mass loading for detonation extinction reduces significantly when the droplet size becomes smaller. It is also found that for the same droplet size, the average detonation speed monotonically decreases with water mass loading. However, detonation speed and pulsating frequency have a non-monotonic dependence on droplet size under a constant water mass loading. (C) 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

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