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A transparent, self-powered photodetector based on p-CuI/n-TiO2 heterojunction film with high on-off ratio

机译:一种基于p-CuI/n-TiO2异质结薄膜的高通断比透明自供电光电探测器

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摘要

Ultraviolet(UV) photodetectors(PDs) can monitor UV radiation, enabling it to be effective for many applications, such as communication, imaging and sensing. The rapid progress on portable and wearable optoelectronic devices places a great demand on self-powered PDs. However, high-performance self-powered PDs are still limited. Herein we display a transparent and self-powered PD based on a p-CuI/n-TiO2 heterojunction, which exhibits a high on-off ratio (similar to 10(4) at 310 nm) and a fast response speed (rise time/decay time = 0.11 ms/0.72 ms) without bias. Moreover, the device shows an excellent UV-selective sensitivity as a solar-blind UV PD with a high UV/visible rejection ratio (R (300 nm)/R (400 nm) = 5.3 x 10(2)), which can be ascribed to the wide bandgaps of CuI and TiO2. This work provides a feasible route for the construction of transparent, self-powered PDs based on p-n heterojunctions.
机译:紫外(UV)光电探测器(PDs)可以监测紫外辐射,使其在许多应用中有效,如通信、成像和传感。便携式和可穿戴光电器件的快速发展对自供电 PD 提出了很高的要求。然而,高性能的自供电PD仍然有限。在此,我们展示了一种基于p-CuI/n-TiO2异质结的透明自供电PD,该PD具有高通断比(在310 nm处类似于10(4))和快速响应速度(上升时间/衰减时间= 0.11 ms/0.72 ms)且无偏置。此外,该器件作为具有高紫外/可见光抑制比(R (300 nm)/R (400 nm) = 5.3 x 10(2))的日盲紫外局部放电表现出优异的紫外选择灵敏度,这可归因于CuI和TiO2的宽禁带。本工作为构建基于p-n异质结的透明自供电PD提供了一条可行的途径。

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