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Enhanced magnetic performance in exchange-coupled CoFe2O4-LaFeO3 nanocomposites

机译:交换耦合CoFe2O4-LaFeO3纳米复合材料的增强磁性能

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Nanocomposite oxide system of (x)CoFe2O4-(100-x)LaFeO3 with different weight percent of core-shell structured CoFe2O4 (x = 0, 20, 40, 50, 80, 100) and LaFeO3 were fabricated, via a two-step sol-gel wet-chemical synthesis technique. The phase formation of the composites was confirmed by x-ray diffraction and the structural parameters of both the phases were attained from the Rietveld refinement results of XRD patterns. The elemental composition and microstructure of the resulting nanocomposites were examined by using energy-dispersive x-ray spectroscopy and high-resolution transmission electron microscopy technique, respectively. The detailed magnetometry studies at 300 K and 5 K reveal that the inter-and intra-phase magnetic interactions affect the saturation magnetization (M (S)), remanence magnetization (M (R)) and coercivity (H (C)) values of this bi-magnetic system. The remarkable feature of 'pinched magnetic hysteresis loop' was evidenced in the (50) CoFe2O4 - (50)LaFeO3 composite, leading to a lesser magnetic loss factor and better magnetic performance of this sample. The report depicts an improved interfacial exchange coupling at 5 K, for the nanocomposites of core-shell morphology and offers an understanding or explanation of improved magnetic performance for the (50)CoFe2O4 - (50)LaFeO3 nanocomposite and opens up an important way to design new multiferroic applications in low magnetic fields.
机译:采用两步溶胶-凝胶湿化学合成技术制备了不同重量百分比的(x)CoFe2O4-(100-x)LaFeO3和LaFeO3的纳米复合氧化物体系。通过X射线衍射证实了复合材料的相形成,并通过XRD图谱的Rietveld细化结果获得了两种相的结构参数。采用能量色散X射线光谱和高分辨透射电子显微镜技术分别研究了纳米复合材料的元素组成和微观结构。在300 K和5 K下详细的磁力测量研究表明,相间和相内磁相互作用会影响该双磁系统的饱和磁化强度(M(S))、剩磁化强度(M(R))和矫顽力(H(C))值。[(50) CoFe2O4 - (50)LaFeO3]复合材料证明了“捏紧磁滞回线”的显著特征,使该样品具有更小的磁损耗因数和更好的磁性能。该报告描述了核壳形貌纳米复合材料在5 K下改进的界面交换耦合,并提供了对(50)CoFe2O4 - (50)LaFeO3纳米复合材料磁性能改进的理解或解释,并为设计新的低磁场多铁性应用开辟了一条重要途径。

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