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COMPARATIVE STUDY OF THE ADSORPTION OF CATIONIC AND ANIONICDYES BY ALUMINUM(III)MODIFIED CLAY

机译:铝(III)改性粘土吸附阳离子和阴离子染料的比较研究

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摘要

Dye removal of industrial and domestic efflu-ents is one of the critical environmental operations, and among many technologies applied in this context. adsorption is known as a process with high potential for removing dyes from wastewater. Although lay-ered clays with a high negative surface charge den-sity are extremely suitable for removing cationic dyes from aqueous solution, they are not effective in the adsorption of anionic dyes in their original form. This study aimed to use Al+ ions, which are widely used in industrial scale as settling or decantation agents in colloidal dispersions, as modifiers in sur-face modification of bentonite clay to make them suitable for adsorption of anionic dyes. In this study, bentonite clay was chosen as an adsorbent and it was modified in the aqueous solution of AlCl3. In addi-tion, cationic dye, methylene blue(MB),and anionic dye, Remazol red RB, were selected as representa-tive dyes, and the influences of variables such as dye concentration, adsorption time and pH on adsorption were investigated. In the case of anionic dye, the ad-sorption efficiency of bentonite clay modified with Al(III)increased, whereas the cationic dye adsorp-tion efficiency decreased, indicating that the modifi-cation is quite effective.
机译:工业和生活废水的染料去除是关键的环境操作之一,也是在这方面应用的众多技术之一。吸附被称为从废水中去除染料的高潜力过程。虽然具有高负表面电荷密度的外层粘土非常适合从水溶液中去除阳离子染料,但它们不能有效地吸附原始形式的阴离子染料。本研究旨在利用工业规模上广泛使用的Al+离子作为胶体分散体中的沉降剂或倾析剂,作为膨润土表面改性的改性剂,使其适用于阴离子染料的吸附。本研究选用膨润土作为吸附剂,在AlCl3水溶液中对其进行改性。此外,选取阳离子染料亚甲蓝(MB)和阴离子染料瑞马唑红RB作为代表性染料,考察染料浓度、吸附时间和pH值等变量对吸附的影响。在阴离子染料的情况下,Al(III)改性膨润土的吸附效率增加,而阳离子染料吸附效率下降,说明改性效果较好。

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