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Influence of application methods on the degradation of permethrin in laboratory, soil aerobic metabolism studies

机译:施用方法对氯菊酯降解的影响 实验室、土壤好氧代谢研究

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AbstractThe effects of application rate, volume, solvent and soil moisture content on the kinetics of mineralization and degradation, of 14C permethrin have been studied in a sandy loam soil under standard laboratory conditions. During the incubation period, up to 32 days, the temperature and moisture level of the soil were controlled. Apart from the effects of application rate, which have been widely reported, application volume had the most significant effect on mineralization rate andT1/2. 14CPermethrin, at a level of a 1 mg kg−1in the soil, applied in 100 μl of methanol, resulted in the evolution of 14 of the applied radiochemical as 14C carbon dioxide over 30 days. The same level applied in 1000 μl mineralized at a faster rate, with 30 14Ccarbon dioxide evolved over 30 days.The test chemical applied to soil in methanol mineralized at a significantly faster rate than a similar concentration applied in ethanol. There was no significant difference when comparing applications made using acetonitrile with those using methanol or ethanol. The addition of formulation ingredients resulted in little or no variation in mineralisation rate compared to an equivalent application volume of methanol/wa
机译:摘要 在标准实验室条件下,研究了施用量、体积、溶剂和土壤含水量对[14C]氯菊酯矿化和降解动力学的影响。在长达32天的潜伏期内,控制土壤的温度和湿度水平。除施用量对矿化速率和T1/2的影响外,施用量对矿化速率和T1/2的影响最为显著。[14C]氯菊酯在土壤中含量为 1 mg kg−1,施用于 100 μl 甲醇中,导致 14% 的施用放射性化学物质在 30 天内演变为 [14C] 二氧化碳。在1000μl中以更快的速度矿化,30%[14C]二氧化碳在30天内释放出相同的水平。在甲醇中施用于土壤的测试化学品的矿化速度明显快于在乙醇中施用的类似浓度。将使用乙腈的应用与使用甲醇或乙醇的应用进行比较时,没有显著差异。与同等施用量的甲醇/wa相比,添加配方成分导致矿化速率几乎没有变化

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