The pure rotational spectrum of thiazole (c-C3H3NS, C-s) has been studied in the millimeter-wave region from 130 to 375 GHz. Nearly 4800 newly measured rotational transitions for the ground vibrational state of the main isotopologue were combined with previously reported measurements and least-squares fit to a complete sextic Hamiltonian. Transitions for six singly substituted heavy-atom isotopologues (C-13, N-15, S-33, S-34) were observed at natural abundance and likewise fit. Several deuterium-enriched samples were prepared, which gave access to the rotational spectra of 16 additional isotopologues, 14 of which had not been previously studied. The rotational spectra of each isotopologue were fit to A- and S-reduced distorted-rotor Hamiltonians in the I-r representation. The experimental values of the ground-state rotational constants (A(0), B-0, and C-0) from each isotopologue were converted to determinable constants (A(0)'', B-0 '', and C-0 ''), which were corrected for effects of vibration-rotation interactions and electron-mass distributions using coupled-cluster singles, doubles, and perturbative triples calculations [CCSD(T)/cc-pCVTZ]. The moments of inertia from the resulting constants (A(e), B-e, and C-e) of 24 isotopologues were used to determine the precise semi-experimental equilibrium structure (r(e)(SE)) of thiazole. As a basis for comparison, a purely theoretical equilibrium structure was estimated by an electronic structure calculation [CCSD(T)/cc-pCV5Z] that was subsequently corrected for extrapolation to the complete basis set, electron correlation beyond CCSD(T), relativistic effects, and the diagonal Born-Oppenheimer correction. The precise r(e)(SE) structure is compared to the resulting "best theoretical estimate" structure. Some, but not all, of the best theoretical r(e) structural parameters fall within the narrow statistical limits (2 sigma) of the r(e)(SE) results. The possible origin of the discrepancies between the best theoretical estimate r(e) and semi-empirical r(e)(SE) structures is discussed. Published under an exclusive license by AIP Publishing.
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