Exposure to ozone can cause several adverse health effects on human beings. Carbon-based filters are usually used for the removal of ozone from indoor air. The main problem with Carbon-based filters technology is the exhaustion of carbon because of irreversible reactions with ozone. Therefore, the knowledge of the service life of filters is crucial for building engineers and designers. Since testing at low indoor concentrations is timeconsuming and expensive, the existing standards suggest experimenting with high concentrations. Thus, predictive models need to be developed to estimate the service life of filters. This work provides a model to estimate the breakthrough curves of three different combined (multi-layer) filters. The model augmented mass transfer equations with a reaction rate model and divided them into interpellet mass transfer and kinetic models. First, the reaction rate parameters were measured by fitting the model onto experimental data of all filters challenged with 9 ppm or 90 ppm of ozone. This was followed by validating the model for lower concentrations. In addition, to show the model validity for real-life application, its prediction was compared with the experimental data collected using the full-scale experimental setup and higher velocity. There was excellent agreement between the model prediction and the experimental results for all filters. Furthermore, an inter-model comparison was performed to determine the importance of different mass transfer steps. The results showed internal diffusion and axial dispersion as rate-limiting steps along with reaction. Finally, a sensitivity analysis was conducted on reaction kinetic parameters, axial dispersion coefficient, external mass transfer coefficient, and activated carbon particle porosity, which indicated negligible effects of external mass transfer and porosity variations.
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