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Further studies of the degradation of the pyrethroid insecticide cypermethrin in soils

机译:拟除虫菊酯类杀虫剂氯氰菊酯在土壤中的降解的进一步研究

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AbstractStudies of the degradation of the pyrethroid insecticide cypermethrin (NRDC 149) and itscis‐ andtrans‐isomers (NRDC 160 and NRDC 159, respectively), have been extended. In soils stored in the laboratory for up to 52 weeks, cypermethrin continued to be degraded by hydrolysis and oxidation. A previously unidentified product has now been identified as the dicarboxylic acid 3‐(2, 2‐dichlorovinyl)‐1‐methylcyclopropane‐1, 2‐dicarboxylic acid. Comparative experiments carried out under indoor and outdoor conditions showed that essentially the same products were formed under these different conditions. However, α‐carboxy‐3‐phenoxybenzyl 3‐(2, 2‐dichlorovinyl)‐2, 2‐dimethyl‐cyclopropanecarboxylate was one minor product detected only under outdoor conditions. Evidence is presented for the further degradation of bound residues arising in soil from cypermethrin treatments. There was limited uptake of the radiolabel into wheat grown in soil contain
机译:摘要对拟除虫菊酯类杀虫剂氯氰菊酯(NRDC 149)及其反式异构体(NRDC 160和NRDC 159)降解的研究已经扩展。在实验室储存长达52周的土壤中,氯氰菊酯继续通过水解和氧化降解。一种以前未鉴定的产品现已被鉴定为二羧酸3-(2,2-二氯乙烯基)-1-甲基环丙烷-1,2-二羧酸。在室内和室外条件下进行的对比实验表明,在这些不同的条件下形成了基本相同的产物。然而,3-(2,2-二氯乙烯基)-2,2-二甲基环丙烷羧酸酯α-羧基-3-苯氧基苄酯是一种仅在室外条件下检测到的次要产物。为氯氰菊酯处理后土壤中产生的结合残基进一步降解提供了证据。放射性标记物在土壤中生长的小麦的吸收有限

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