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Degradation of the dicarboximide fungicides iprodione, vinclozolin and procymidone in Patumahoe clay loam soil, New Zealand

机译:新西兰Patumahoe粘壤土中二甲酰亚胺类杀菌剂异菌脲、长春唑啉和原糖脲的降解

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AbstractAn enhanced rate of degradation of the dicarboximide fungicides iprodione and vinclozolin was induced in the laboratory in Patumahoe clay loam soil by adding three successive applications of fungicide. Enhanced degradation of the dicarboximide fungicide procymidone could not be induced. Following the first fungicide treatment, the time to 50 loss of iprodione was greater than 35 days; for vinclozolin the time to 50 loss was 22 days. The rate of degradation accelerated with successive applications until, after a third successive application of fungicide, the time to 50 loss of iprodione was only two days and none was detectable at seven days. For vinclozolin, after the third successive application of fungicide, 50 loss occurred after 35 days. By comparison, minimal loss of procymidone was detected after 35 days following each of two successive soil treatments.The induction of enhanced degradation of iprodione and vinclozolin in this soil in the laboratory may explain the observed loss of field control of onion white rot disease. Degradation of iprodione occurred in non‐sterile soil but not in sterile soil, indicating that microbial involvement may be responsible for the degradation of iprodione and vinclozolin in soi
机译:摘要在帕图马霍粘壤土中连续施用3种杀菌剂,提高了双甲酰亚胺类杀菌剂异菌脲和长春唑啉的降解速率。双甲酰亚胺杀菌剂原嘧啶酮的降解增强不能诱导。在第一次杀菌剂处理后,异菌脲损失50%的时间大于35天;对于长春唑啉,损失50%的时间是22天。连续施用后降解速度加快,直到连续第三次施用杀菌剂后,异菌脲损失50%的时间仅为2天,7天时未检测到任何残留物。对于长春唑啉,在连续第三次施用杀菌剂后,35天后损失了50%。相比之下,在连续两次土壤处理后35天后检测到丙啶酮的最小损失。在实验室中诱导异菌脲和长春唑啉在该土壤中增强降解可以解释观察到的洋葱白腐病田间控制丧失的原因。异菌脲的降解发生在非无菌土壤中,但在无菌土壤中未发生,表明微生物的参与可能是导致异菌脲和长春唑啉降解的原因。

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