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NATURAL PRODUCT REPORTS A JOURNAL OF CURRENT DEVELOPMENTS IN BIOORGANIC CHEMISTRY VOLUME 12 NUMBER 2 APRIL 1995 Articles that will appear in forthcoming issues include Marine Natural Products D J Faulkner Fever Few: Chemistry and Biological Activity D W Knight Recent Progress in the Chemistry of Non-monoterpenoid Indole Alkaloids M Ihara and K Fukumoto Natural Sesquiterpenoids B M Fraga Isoflavanoids and Neoflavonoids D M X Donnelly and G M Boland Amaryllidaceae and Sceletium Alkaloids J R Lewis Journal of Chemical Research, Issue 3,1995 Other papers in the subject areas covered by J. Chem. SOC.are published in synopsis/microform format in J. Chem. Research. For the benefit of readers of J. Chem. SOC.,the contents list of J. Chem. Research (S}, Issue 3, is reproduced below.83 On the Mechanism of Formation of l13,4-Thiadiazol-2(3H )-ones in the Reaction of Hydrazonoyl Halides with 1,3.4-0xadiazole- (M0646) 2(3H)-thiones Mosselhi A. N. Mosselhi, Magda A. Abdallah, lkhlass NI. Abbas, Sohair 2. Mohammed and Ahmad Sami Shawali 84 Kinetic Study of the Molecular Chemiluminescence SrBr(A 2111,2,3.2r and the Atomic Resonance Fluorescence B zX+-X 2Z+) (M0601) Sr(5 3P, -.5 'So) following the Pulsed Dye-laser Generation of Sr(5 3P,) in the presence of CH,Br, Stephen Antrobus, David Husain, Jie Lei, Fernando Castaho and Maria N. Sanchez Rao 86 Formation of a Thiirane and a 1,3-Oxathiolane S-Oxide from Thermolysis of a Thiosutfinic S-Ester Hoh-Gyu Hahn and Wha (M0630) Suk Lee 88 Difunctional Heterocycles : a Convenient Synthesis of Novel Bis(dihydrooxadiazoly1) Ethers from Bis(hydrazinocarbonylary1) (M0653) Ethers Ahmed H.M. Elwahy 90 Crystal and Molecular Structures of 2,2'-Dibromo-4,4'-dinitro-, 2,2'-Dibromo-4,4'-bis(acetylamino)-and 3,3'-Diamino-4,4'-dinitro-(M0667) diphenyl Sulfides Thorsten Link, lnken Eggers and Gunter Klar 92 Absolute Stereochemistry of Desertorins, Bicoumarins from Emericella desertorum Ken-ichi Kawai, Motoo Shiro, and (M0701) Koohei Nozawa 94 Infrared Spectral Study and Semiempirical Calculations of the Thermal Decomposition Pathways of Some Substituted (A40686) Furandiones Jean-Pierre Aycard, Hubert Bodot, Mihaela Hillebrand, Mohamed Hnach, Thomas Y. "Guessan, Eugen Segal, tulia Purcea and Elena Volanschi 96 Heterocyclic Fused Rings with Bridgehead Nitrogen Atoms: a Convenient Route to 1,2,4-Triazol0[5,1-c] [1,2,4]triazine, 1,2,4- I-) Triazino[4,3-b] indatole and l12,4-Triazino[4,3-aJ benzimidazole Derivatives Ahmad M.Farag 98 Kinetics of the Reaction of Malononitrile with Alkyl Nitrites (-) Emilia iglesias 100 Activated Nitrites in Heterocyclic Synthesis: Synthesis of Several New 9-Substituted Pyrano-l,2,4-triazolopyrimidine Derivatives (-) Ahmed M. El-Agrody and Saber M. Hassan 102 Enantioselective Synthesis of Diethyl ( + )-(2S,3S )-trans-2,3-Epithiosuccinate (-) Andreas C. Korn and Luis Moroder 104 A Convenient One-flask Synthesis of Vitamin K (-) Hsi-Hwa Tso and Yu-Jiun Chen 106 A Convenient Synthesis of Phenylsulfanyl- and Methylsulfanyl-(nitro)methane (-) Wojciech Karpiesiuk and Wojciech Sas 108 Dithioacetalisation catalysed by an Acidic lon-exchange Resin (-) Amiya Krishna Maiti, Kalyan Basu and Prantosh Bhattacharyya 1 10 Reassignment of the Structure of myo-lnositol Monophosphatase Inhibitor L-671,776 Pietro Ferrari, Stefania Stefanelli and (-) Khalid Islam 112 The 7-cis Effect in the Telluriurn-125 Nuclear Magnetic Resonance Spectroscopy of Substituted Vinylic Tellurides Ivan P.de (-) Arruda Campos, Helio A. Stefani, Luiz C. Roque, Marcel A. Montoro and AntGnio L.Braga 114 A Convenient Synthesis of 2-Benzylindoles (-) Raghao S.Mali, Kantipudi N. Babu and Prakash G. Jagtap 116 A Reassignment of the Structure of 'Bakuchicin' (-) Hamish McNab N.B. The numbers in parentheses, prefaced by MI indicate the first frame occupied by the fu//-text version of the paper in J.Chern. Research (MI. Where no such number is given, the paper as published in J. Chern. Research (S/ is complete in itself, and there is no extra material in Part M. Ninth European Symposium on Organic Chemistry Warsaw, Poland June 18-23,1995 ESOC IX Topics: Synthetic Organic Chemistry Physical and Bio-Organic Chemistry -~ Lectures will be presented by prominent chemists from Posters are invited to submission. Financial support such all over Europe. as sponsorship, publicity in the programme or W. Adam (Wiirzburg, Germany) participation in the exhibition is gratefully welcomed M. Bachi (Rehovot, Israel) For further details please contact F. Camps (Barcelona, Spain) Prof.M.M&osza (President) B. Castro (Paris,France) Institute of Organic Chemisuy M.Chon (Marseille,France) Polish Academy of Sciences S. G.Davis (Oxford, U.K.) Kasprzaka 44,PL 01-224 Warszawa (Poland) F. DiFurio (Padova, Italy) TelFax: 48 (22) 32 66 81 J. B. Engberts (Groningen, The Netherlands) Fax: 48 39120238 J. W.Engels (Frankfurt am Main, Germany) A. Eschenmoser(ziirich, Switzerland) INTERNATIONAL SCIEhTlFlC CO-E F. Hammerschmidt (Vienna, Austria) P. Ahlberg (Sweden),w*Hartw% (wqw,-Y) Y. Apeloig (Israel), EL kJmgensen (Aaxthus, Denmark) D. Endm (Germany), A. Johczyk (Warsaw, Poland) J. Font (Spain), N. delliimpe (Ghat, Belgium) A. Krief (Belgium), P. Kiiadig (Genewa,Switzerland) M.Mikolajczyk (Poland), G. L'abbe' (Leuwen, Belgium) 0.Nefedow (Russia), A. Liptak (Debrecen, Hungary) G.Scorrano (Ialy), G. Mapusson (Lund, Sweden) P.Sinay (France), G. Maier (Giessen, Gexmanyy) V. Sunjic (Croatia), G. MeUoni (Sassari, Italy) C. Tamm (Switzerland)V. Minkin (Rostov, Russia) J. Mulzer (Berlin, Gennany) J. F. Normat (Paris,France) NATIONAL 0RGA"G COMMITTEE: C.Pzrlomo (San Sebastian, Spain) M.Chmielewski (Warszawa), A. Ricci (Bologna, Italy) J. GawroWi (Pozna~I), M. Sbeves (Rehovot, Israel) J. Jurczak (Warszawa), E. Serebrjakov (Moscow, Russia) A. Konowd (Warszawa), W. J. Stec (L6d2, Poland) M. M&osza (Warszawa), I. Stibor (Praque, Czech-Republic) J. Wchalski (LO&), Ch. J. M. Stirling (Sheffield.U.K.) J. Mochowski (Wroclaw), I. Tvaroska (Bratislawa, Slovakia) J. Rachod (Gdarisk), P. Vogel (Lausanne, Switzerland) J. Suwitiski (Gliwice) N.S.Ze6row (Moscow,Russia) M.Zupan (Ljubljana, Slovenia) THE NEW SOUTH WALES SOUTHERN HIGHLANDS CONFERENCE ...........ON HETEROCYCLIC CHEMISTRY Milton Park ...... Bowral 3 -5 September 1995 /\HC-0-N A two day fully residential conference in the style of the Biirgenstock, Gordon and Grasmere conferences on the general theme of heterocyclic chemistry. Topics to include natural products and cover synthetic, organometallic, pharmacological, stereochemical and commercial aspects. 0 Six invited lectures 0 Continuous poster session 0 Discussion in a relaxed atmosphere Further details from: Professor David StC Black School of Chemistry,The University of New South Wales Sydney NSW 2052 Australia Telephorze:+(612) 385 4657 Fax: +(612) 662 2835 E-mail: D.Black@ urzsw.edu.au DEPARTMENT OF ORGANIC CHEMISTRY -THE UNIVERSITY OF NEW SOUTH WALES EUCHEM Conference Cycloadditions and Related Reactions: Theory and Practice Vulcano Island, Italy, 21-24 June 1995 The scientific programme will consist of lectures, and oral and poster presentations.Keynote lectures (60 min) and invited oral presentations (30 min) will be given by experts in the field. Additional papers will be selected for oral presentations (15 min) from submitted abstracts. International Scientific Committee D. Bellus (Basel, Switzerland) R.Huisgen (Munchen, Germany) A. Dondoni (Ferrara, Italy) P. Potier (Gif-sur-Yvette, France) J. Elguero (Madrid, Spain) C.W. Rees (London, UK) P. Grunanger (Pavia, Italy) G. Stagno d’ Alcontres, President (Messina, Italy) Plenary and Invited Lecturers S. Blechert (Berlin, Germany) Y. Langlois (Orsay, France) A. Brandi (Firenze, Italy) J. Mattay (Munster, Germany) F. Cozzi (Milano, Italy) W. Oppolzer (Geneva, Switzerland) G. Desimoni (Pavia, Italy) C. Palomo (San Sebastian, Spain) L. Fisera (Bratislava, Slovak Republic) J. Plumet (Madrid, Spain) T. Gallagher (Bristol, UK) J. Rip011 (Caen, France) D. S. Grierson (Gi f-sur-Y vette, France) J. Sauer (Regensburg, Germany) R. Herges (Erlangen, Germany) J. F. Stoddart (Birmingham, UK) P.R. Jenkins (Leicester, UK) L. F. Tietze (Gottingen, Germany) J. Jurczak (Warsaw, Poland) For a copy of the Second Circular and Application Form, contact Professor Mario Gattuso, EUCHEM Conference, Dipartimento di Chimica organica e biologica dell’universiti, Salita Speronc 3 1, S. Agata, 98 166 Messina, Italy; Tel. +39 90 392038; Fax +39 90 392840; E-mail gattuso@imeuniv.unime.it 5th European Symposium on Organic Reactivity ESOR-V Santiago de Compostela Spain 16-21 July 1995 Progress in Experimental, Computational and Theoretical Studies of Organic Reactivity Plenary Lecturers J.-L. M. Abboud, Instituto de Quimica Fisica Rocasolano, Spain C. Bernasconi, University of California, Santa Cruz, USA J. Berth, Universitat Autonoma de Barcelona, Spain U.Edlund, University of Umea, Sweden W. P. Jencks, Brandeis University, USA A. J. Kirby, Cambridge University, UK A. J. Kresge, University of Toronto, Canada C.Reichardt, Philipps-Universitat Marburg, Germany J.-M. Savbant, Universite Denis Diderot, France J. W. Verhoeven, Universiteit van Amsterdam, The Netherlands A. Pross, Ben-Gurion University, Israel F. Di Furia, Universitk di Padova, Italy Contact: Dr J. Rarn6n Leis, ESOR V, Facutade de Quimica, Departamento de Quirnica Fisica, Universidade de Santiago de Compostela, 15706 SANTIAGO, SPAIN Fax +34 81 595012. Tel+34 81 591078. E-mail qfjrleis@usc.es FOURTH INTERNATIONAL SYMPOSIUM ON CARBANION CHEMISTRY (ISCC-4) Saturday, August 12 = Wednesday, August 16, 1995 Fort Collins, Colorado, U.S.A.The ISCC-4 meetin will consist of 11 lenary lectures of one hour each, 14 invited lectures of 30 minutes eac$ and opportunit For approximately 100 osters. The theme of the conference will focus on all as ects or carbanion chemistry (synt Retic, mechanistic, structure, and the0 ). Posters on any o!i!these sub'ects will be accepted until the capacit Y is reached. These w% be prominently displayed in the lecture area and specific times wil be reserved for discussions with the posters' authors. The individuals who have accepted an invitation to speak are: William F. Baile , U.S.A. Z. Jedlinski, Poland Jos6 Barluenga, 8pain Steven R. Kass, U.S.A. Walter Bauer, Germany Paul Knochel, Germany Peter Beak, U.S.A.Alain Krief, Bel,' *ium J. Micheal Chong, Canada E. Peter Kiindig, Switzerland M. Cin uini, Italy David 8. Collum, U.S.A. Daniel L. Comins, U.S.A. Alessandro Dondoni, Italy Reuben D. Rieke, U.S.A. David A. Evans, U.S.A. Eric J. Thomas, U.K. S. Florio, Ital Peter Wipf, U.S.A. Reinhard W. 4;offmann, Germany Y. Yamamoto, Japan A. H. Hoveyda, U.S.A. Or anizin Committee: A. I. Meyers (Fort Collins) Symposium Chairman, M. T. Reetz (dlheimf P. Kocienski (Southampton , A. Alexakis (Paris), F. Bernardi (Bolo na), G. Boche (Marburg), F. Bordwell (Evanston), 4. Cozzi (Milano), C.H. Depuy (Boul 5er), T. Durst (Ottawa), T. Mukaiyama (Tokyo), G. H. Posner (Baltimore), M. Schlosser (Lausanne) Due to space limitations, the conference attendance will be limited to 300 persons.For further information on the conference, address: ISCC-4 Office of Conference Services Colorado State Universit Fort Collins, Colorado 8B523 U.S.A. Telephone (303) 49 1-6222 Fax (303) 491-0667 15th International Congress of Heterocyclic Chemistry Taipei, August 6-11, 1995t. t7 Plenary Speakers Organizing Committee TAIPEI 1985 C. H. Heathcock C.-K. Sha (Chairman) Y. It0 T.-S. Chou (Cochairman) Topics Y. T. Lee K.-C. Liu (Cochairman) S. V. Ley C.-C. Han (General Secretary) K. Mori S.-S. P. Chou, J.-M. FangOrganic Synthesis in G. R. Newkome Y.-S.Ho~,R. J. R. HWU Heterocyclic Chemistry R. Noyon Johnsee Lee, C.-C. Liao C. W. Rees T.-Y. Luh, H.-J.Tie Asymmetry and Heterocycles J. Wang, T.-K. YangE. Vopel C.-L. S. M. WeinrebHeterocyclic Pharmaceuticals and C.-H. Wong Honorary Advisory Committee Agrochemicals Molecular Recognition by Invited Speakers J. Berpman, A. Dondoni, J. Elguero Heterocycles T. Kappe, G. L'abbk, S. Lang M.D. Bachi J. Barluenga H. W. Moore, H. Neunhoeffer Bioorganic Chemistry of G. Bern5t.h D. Black A. Padwa, W. Pfleiderer Heterocycles E. Block 3.S. Bradshaw T.-S.Chou P. Confalone Address for Correspondence New Heterocyclic Materials F. Effenberger R.L. Elsenbaumer J.-M. Fang B. Ganem Professor Chin-Kang Sha Miscellaneous M. Hanack D.3. Hart Department of Chemistry H. Hiemstra A.B. Holmes Hsinchu 300, Taiwan, R.O.C. Sponsored by T. Hudlicky R.J.R.Hwu Tel: 886-35-722427 D. H. Kim S. Kim Fa: 886-35-725870 International Society of N. De Kimpe E. Kimura E-mail: &ha@ chem.nthu.edu.tw Heterocyclic Chemistry M. Lautens G.-Q. Lin Y.-I. Lin H.-J. Liu International Union of Pure and C. Moody W. Pearson Applied Chemistry R. Pellicciari G.S.R. Subba Rao D.N. Reinhoudt A.G. Schultz The Chemical Society Located T. Shimidzu Y. Thebtaranonth Taipei L.F. Tietze M. Tisler H.N.C. Wong Post-Congress Symposium Hong Kong International Symposium s s& AE on Heterocyclic Chemistry August 13-16, 1995 Topics Plenary Speakers Invited Speakers Biologically Active Heterocycles A.G.M. Barrett M.G. Banwell M.A. Brimble D.L. Boger E.C. Constable R.K. Haynes Heterocyclic Ligands in C.M.Che A.B.Holmes Z.T. Huang Asymmetric Synthesis W.H. Pearson D.W. Knight A.W.M. Lee H. Takaya T.-Y. Luh Y. Nagao New Methods of Heterocyclic S.M. Weinreb A. Padwa A. Pfaltz Synthesis C.-K. Sha M. Shibasaki V. Snieckus W.S. Tian E.Voge1 Y.L. Yu Address for CorrespondenceDr. R.M. Letcher, Chairman, Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong. Tel: 852-2859-21 50 Fax:852-2857- 1586 E-mai1:hrsclrm @hkucc.bitnet International Society of Heterocyclic Chemistry HONG KONG INTERNATIONAL SYMPOSIUM ON HETEROCYCLIC CHEMXSTRY August 13-16 1995 Department of Chemistry, The University of Hong Kong, Hong Kong Topics *Biologically Active Heterocycles *Heterocyclic Ligands in Asymmetric Synthesis *New Methods of Heterocyclic Synthesis Plenary Speukers A.G.M. Barrett Imperial College, London D.L. Boger Scripps Research Institute, La Jolla C.M. Che University of Hong Kong W.H. Pearson University of Michigan H. Takaya Kyoto University S.M. Weinreb Pennsylvania State University Contact: Dr R.M. Letcher, Chaiman, Department of Chemistry, The University of Hong Kong, Pokfulani Road, Hong Kong Tel. (+852) 859 2150. Fax. (+852) 857 1586 E-mail hrsclrm @hkucc.bitnet