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Changes in the Surface Morphology and the Barrier Properties of the Silicate Deposited Nylon 6 Films Subjected to Various Deformations

机译:硅酸盐沉积尼龙6薄膜在各种变形作用下的表面形貌和阻隔性能的变化

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摘要

Damages of SiO_x layer on the SiO_x deposited nylon 6 film caused by the Gelboflex tests, abrasion, and creasing were examined by dyeing, AFM observation and measurements of H_2 permeation rates. The number and the extent of micro cracks on the SiO_x layer increased with the repetition of Gelboflex and the H_2 barrier property was deteriorated. Abrrasion by the polishing paper caused a lot of long and deep scratches on the SiO_x layer and the H_2 barrier by SiO_x layer was almost completely lost. Even mild rubbing by the cotton cloth damages the SiO_x layer and the H_2 barrier property of SiO_x deposited nylon 6 film was more deteriorated with increasng number of rubbing. Creased SiO_x deposited nylon 6 films have micro cracks on the creased line. Such damages caused by the Gelboflex tests, abrasion, and creasing were less serious when the SiO_x layer on the SiO_x deposited nylon 6 film was laminated with a polyethylene film. Even though the micro crack was caused on the SiO_x layer by the large deformation, the polyethylene film laminated oflds the SiO_x layer and hinders further progress of cracks.
机译:通过染色、AFM观察和H_2渗透率测量,研究了Gelboflex试验对SiO_x沉积尼龙6薄膜SiO_x层的损伤、磨损和折痕。随着Gelboflex的重复,SiO_x层微裂纹的数量和程度增加,H_2阻隔性能变差。抛光纸的磨损在SiO_x层上造成了许多又长又深的划痕,SiO_x层的H_2屏障几乎完全消失了。即使棉布轻轻摩擦也会破坏SiO_x层,沉积SiO_x尼龙6薄膜的H_2阻隔性能随着摩擦次数的增加而更加恶化。褶皱SiO_x沉积的尼龙 6 薄膜在褶皱线上有微裂纹。当SiO_x沉积的尼龙 6 薄膜上的SiO_x层与聚乙烯薄膜层压时,由 Gelboflex 测试、磨损和折痕引起的此类损坏不那么严重。尽管微裂纹是由大变形在SiO_x层上引起的,但层压的聚乙烯薄膜阻碍了裂纹的进一步发展SiO_x层。

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