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首页> 外文期刊>Journal of optical technology >Nonlinear optical properties of associates of dyes with zinc sulfide nanoparticles
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Nonlinear optical properties of associates of dyes with zinc sulfide nanoparticles

机译:染料与硫化锌纳米颗粒缔合物的非线性光学性质

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The Z-scanning method is used to study nonlinear absorption in associates of colloidal zinc sulfide nanoparticles and organic dyes. The nonlinear absorption coefficients of associates of various dyes thionine, erythrosine, and a pyridine salt of 3,30-di-(gamma-sulfopropyl)-4-4',5-5'-dibenzo-9-ethylthiacarbocyanine betaine and ZnS nanoparticles with a mean size of 2 nm are obtained at wavelengths of 1064 and 532 nm of 40-ps pulsed radiation of a YAG:Nd3+ laser. It is presumed that the nonlinear absorption of the ZnS nanoparticles at 1064 nm is caused by three-photon excitation of luminescence centers. The association of the dye molecules with the ZnS nanoparticles reduces the dip in the Z-scanning curves, and this is caused by the acceptor properties of the dyes and probably by the transfer of electron excitations from the luminescence centers of the ZnS nanoparticles to the dye molecules. (c) 2018 Optical Society of America.
机译:Z扫描法用于研究胶体硫化锌纳米颗粒和有机染料的非线性吸收。在YAG:Nd3+激光器的40 ps脉冲辐射波长为1064和532 nm时,获得了各种染料[硫氨酸、赤藓红和3,30-二(γ-磺丙基)-4-4',5-5'-二苯并-9-乙基硫代羰花青甜菜碱的吡啶盐]和平均尺寸为2 nm的ZnS纳米颗粒的缔合物的非线性吸收系数。据推测,ZnS纳米颗粒在1064 nm处的非线性吸收是由发光中心的三光子激发引起的。染料分子与ZnS纳米颗粒的结合减少了Z扫描曲线的下降,这是由染料的受体性质引起的,也可能是由ZnS纳米颗粒的发光中心向染料分子的电子激发转移引起的。(c) 2018 年美国光学学会。

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