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Temperature dependence of constitutive behaviour for solid-state sintering of alumina

机译:氧化铝固态烧结本构行为的温度依赖性

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摘要

A discontinuous hot forging approach was employed in this study in order to extract the temperature dependence of the constitutive sintering parameters for alumina. Uniaxial viscosity and sintering stress were both experimentally obtained as functions of density and temperature for an isotropic microstructure. The activation energy for the viscosities was determined to be approximately 480 kJ/mol by means of an Arrhenius-type plot incorporating the grain size data at varying temperatures. It was indicated that creep and densification during sintering of alumina under a small uniaxial load were both grain boundary diffusion controlled kinetic processes. The same temperature dependence of uniaxial and bulk viscosities was demonstrated, indicating that the viscous Poisson's coefficient is temperature-independent. The sintering stress of a porous compact was experimentally identified as independent of temperature, but inversely proportional to grain size, in agreement with theoretical predictions.
机译:本研究采用不连续热锻方法提取氧化铝本构烧结参数的温度依赖性。通过实验获得了各向同性微观结构的单轴粘度和烧结应力作为密度和温度的函数。通过结合不同温度下晶粒尺寸数据的阿伦尼乌斯型图,确定粘度的活化能约为 480 kJ/mol。结果表明,氧化铝在小单轴载荷下烧结过程中的蠕变和致密化都是晶界扩散控制的动力学过程。证明了单轴粘度和整体粘度的温度依赖性相同,表明粘性泊松系数与温度无关。实验发现,多孔压块的烧结应力与温度无关,但与晶粒尺寸成反比,这与理论预测一致。

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