This paper presents the results of a study of the pulsed cathodoluminescence of samples of neodymium-doped yttrium aluminates. It is found that the d-f emission bands of the Nd~(3+) ion dominate the spectrum of yttrium aluminum garnet in the visible region. The relative intensities and widths of the d-f bands vary as the crystal structure changes, and new luminescence bands appear. The luminescence bands of Nd~(3+) in the yttrium aluminum garnet and orthorhombic yttrium monoaluminate structures are identified. It is proposed to use two regions of the emission bands of Nd~(3+) in yttrium aluminum garnet as analytical bands to determine the concentration of the cubic phase: those at _1 D 350-500 nm and _2 D 501-650 nm.
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机译:本文介绍了对掺钕铝酸钇样品的脉冲阴极发光的研究结果。研究发现,Nd~(3+)离子的d-f发射带在可见光区主导着钇铝石榴石的光谱。d-f波段的相对强度和宽度随着晶体结构的变化而变化,并出现新的发光波段。鉴定了钇铝石榴石和斜方晶系钇单铝酸盐结构中Nd~(3+)的发光带。建议使用钇铝石榴石中Nd~(3+)发射带的两个区域作为分析带来确定立方相的浓度:_1 D 350-500 nm和_2 D 501-650 nm处的带。
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