DIFFERENTIATING TOURMALINE SPECIES VIA CHEMISTRY AND REFLECTANCE SPECTROSCOPY AT THE GIANT COPPER PORPHYRY DEPOSIT AND ASSOCIATED TOURMALINE BRECCIA PIPES: TESTING TOURMALINE AS A MINERAL VECTOR

摘要

The A.M. breccia is part of the Giant Copper porphyry deposit in southern British Columbia. It is the only well-defined zoned tourmaline breccia pipe in the Canadian Cordillera. Tourmaline is a common alteration mineral within the A.M. breccia and is spatially associated with Cu mineralization. Observed changes in tour?maline chemistry range from alkali (schorlitic-dravitic) to calcic (feruvitic-uvitic). Tourmaline subspecies vary based on their spatial location within the A.M. breccia. Tourmaline outside of the pipe contains higher concen?trations of Mg, whereas tourmaline preferentially incorporates Fe within the pipe. These chemical variations are indistinguishable in hand specimens. Spectral reflectance data were collected from 587 tourmaline grains to determine if discerning chemical changes in tourmaline can be made field-based and thus more cost-effec?tive. Spectral reflectance differentiates tourmaline associated with mineralization and breccia textures from tourmaline occurring distal to the pipe contact or within barren tourmaline breccia pipes. Fe-rich tourmaline within the A.M. breccia shows spectral characteristics of end-member schorl (Fe-rich) spectra. Tourmaline distal to the A.M. breccia and within barren pipes demonstrates spectra of end-member dravite (Mg-rich). This grouping suggests that tourmaline subspecies can be inferred by spectral reflectance, enhancing the effi?ciency of tourmaline as a mineral vector. Tourmaline was also identified via airborne spectral surveys. However, the airborne spectral survey did not identify the end-member spectral properties identified by in situ analysis. Airborne spectral surveys can rap?idly identify tourmaline breccia pipe exposures and expedite early stages of exploration in ore districts where tourmaline is a known gangue mineral.