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首页> 外文期刊>Journal of Geophysical Research, D. Atmospheres: JGR >New Insights Into the Role of Atmospheric Transport and Mixing on Column and Surface Concentrations of NO2 at a Coastal Urban Site
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New Insights Into the Role of Atmospheric Transport and Mixing on Column and Surface Concentrations of NO2 at a Coastal Urban Site

机译:New Insights Into the Role of Atmospheric Transport and Mixing on Column and Surface Concentrations of NO2 at a Coastal Urban Site

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Abstract We use a multi‐year record of Pandora‐derived NO2 total column abundance in Boston to examine the influence of atmospheric transport on column NO2 and its surface concentrations during the warm season in a coastal urban environment. We derive tropospheric NO2 estimates from the total column with a measurement‐model fusion approach using near‐real‐time estimates of stratospheric NO2 from NASA's Goddard Earth Observing System Composition Forecast model system and find the average influence of stratospheric NO2 at this urban site can be 30%–70% depending on season and time of day. Sea breeze days tend to exhibit rapid temporal variability in the column that which can go in the opposite direction of changes in surface NO2 concentrations. By comparing tropospheric NO2 with surface concentrations, we constrain the role of boundary layer entrainment processes in the evolution of surface NO2 concentrations, while highlighting the value of column measurements in identifying sea breeze frontal dynamics. We estimate an apparent equal mixing layer height of NO2 and infer that surface NOx emissions remain concentrated near the surface regardless of atmospheric stability regime. When comparing the Pandora‐ to TROPOMI‐derived column NO2 measurements, we find that sea breeze days present a unique challenge likely due to higher spatial heterogeneity in NO2 and the meteorology involved that is not well represented in retrieval inputs. Our observations provide new insights into column and surface variability of NO2 which will be relevant to interpreting geostationary observations, especially in coastal urban locations.
机译:我们使用多年记录的抽象潘多拉NO2总列丰富波士顿研究大气的影响列NO2和其表面上运输浓度在温暖的季节沿海城市环境。NO2估计从总列测量模型融合方法使用在平流层NO2的实时估计来自美国宇航局戈达德地球观测系统组合预测模型系统和发现平均的影响平流层NO2在这城市站点可以根据季节和30% - -70%每天的时间。快速颞可变性的列可以去相反的方向的变化在表面NO2浓度。对流层NO2浓度与表面,我们限制边界层夹带的角色表面NO2进化的过程浓度,而突出的价值列测量识别海风额动力学。混合层高度NO2和推断表面氮氧化物排放仍集中在无论表面大气稳定政权。TROPOMI派生列NO2应承担的测量,我们发现海风天提供一个独特的挑战可能由于NO2更高的空间异质性和涉及到的气象,并不好在检索输入。提供新的见解列和表面NO2的变化相关解释同步观测,特别是在沿海城市地区。

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