Cobalt Doped Sulfonated Polyaniline with High Electrocatalytic Activity and Stability for Oxygen Evolution Reaction

摘要

The oxygen(OER)evolution reaction plays a crucial role for storage of renewable energy sources but,active sites of the active electrocatalysis remain in challengeable.In this work,we have developed sulfonated polyaniline(SPANI)coordinated with Co sites to investigate the OER process.To improve the electrical conductivity and electrocatalytic efficiency towards OER herein,we report Co@SPANI synthesized by solvothermal method.The different physical characterization(SEM,TEM,XRD,IR,XPS and UV-DRS)and electrochemical methods(voltammetry,chronopotentiometry and EIS)have been used to characterize Co@SPANI materials and examined the correlation of materials with activity.The cobalt doped SPANI(Co@SPANI-800)exhibits higher electrocatalytic activity,showing smaller Tafel slope of 167mVdec~(-1)with lower over-potential of 312 mV at 10 mAcm~(-2)in 1 M KOH,which reveal that abundant Co-metal sites remarkably supporting the OER activity.Co@SPANI-800 exhibits exceptional OER performances and durability over 200 h with loss of <3.5% in alkaline medium.At 1.54 V,solar powered water electrolysis confirmed the effectiveness of newborn electrocatalyst in solar energy to hydrogen energy conversion.Therefore,this work offered new path for designing materials as self-supporting electrode for water splitting and for other potential applications.