The work demonstrates that the quadrupolar nature of acceptor-donor-acceptor pyrrolo[3,2-b]pyrrole systems can be substantially modified via the formation of boron-nitrogen (B-N) bonds between peripheral CN groups and B(C6F5)3.This coordination enables a strong bathochromic shift of emission for both the solid crystalline state as well as in certain solvents.The B-N complex,or co-crystal,was effectively isolated from the reaction between a pyrrolo[3,2-b]pyrrole with two cyanophenyl moieties and tris(pentafluorophenyl)borane (TPFB),which were mixed in non-polar solvents or prepared via liquidassisted solid-state synthesis in a ball mill.An investigation of the structure-property relationship confirmed that the intermolecular B-N bond influences the bathochromic shift in the absorption and emission spectra and that crystallizationinduced emission enhancement was observed owing to the benefits of the molecular packing style and the intermolecular C-H···F interactions.The postsynthetic strategy involves hybridization of molecules on a molecular level,whi
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