New Type of Eco‐Friendly Polymeric Dye by Covalently Bonding Anthraquinone into Polyphenylsulfone

摘要

Abstract Eco‐friendly polymeric dyes with excellent thermal stability, good mechanical performance, and robust chemical stability are highly desired for their diverse and practical applications in food, medicine, electronics and aerospace, etc. However, it remains a big challenge to develop them. Herein, a novel type of eco‐friendly polymeric dye is fabricated by covalently bonding anthraquinone chromophores onto polyphenylsulfone at a molecular level. The obtained polymeric dyes exhibit excellent thermal stability, with a weight loss of 5% at temperatures above 500?°C in air and negligible changes in both color appearance and transparency after being treated at 200?°C in air for 8?h, good mechanical performance with a tensile strength around 70?MPa, and robust chemical stability with demonstrated insolubility and very outstanding colorfastness and anti‐permeability against strong acidic or basic solutions for 7?days at room temperature. These outstanding properties make these polymeric dyes suitable for use in harsh conditions, exceeding existing polymeric dyes, which makes them good to use in some special engineering plastics.