Thickness dependent transition from the 1T ' to Weyl semimetal phase in ultrathin MoTe2: electrical transport, noise and Raman studies

摘要

Bulk 1T '-MoTe2 shows a structural phase transition from the 1T ' to Weyl semimetallic (WSM) T-d phase at similar to 240 K. This phase transition and transport properties in the two phases have not been investigated on ultra-thin crystals. Here we report electrical transport, 1/f noise and Raman studies on ultra-thin 1T '-MoTe2 (similar to 5 to 16 nm thick) field-effect transistor (FETs) devices as a function of temperature. The electrical resistivities for a thickness of 16 nm and 11 nm show maxima at temperatures of 208 K and 178 K, respectively, making a transition from the semiconducting to semi-metallic phase, hitherto not observed in bulk samples. Raman frequencies and linewidths for an 11 nm thick crystal show a change around 178 K, attributed to the additional contribution to the phonon self-energy due to the enhanced electron-phonon interaction in the WSM phase. Furthermore, the resistivity at low temperature shows an upturn below 20 K along with the maximum in the power spectral density of the low frequency 1/f noise. The latter rules out the metal-insulator transition (MIT) being responsible for the upturn of resistivity below 20 K. The low temperature resistivity follows rho proportional to 1/T, changing to rho proportional to T with increasing temperature supports electron-electron interaction physics at electron-hole symmetric Weyl nodes below 20 K. These observations will pave the way to unravel the properties of the WSM state in layered ultra-thin van der Waals materials.