Aircraft observations of rapid meridional transport from the tropical tropopause layer into the lowermost stratosphere: Implications for midlatitude ozone

摘要

Meridional transport from the tropics redistributes ozone and water vapor at middle and high latitudes. In situ measurements of water vapor, CH_4, and N_2O, acquired aboard the NASA ER-2 aircraft during January-March 2000 in a campaign to survey the Arctic vortex, are used to examine transport into the lowermost stratosphere in the context of middle- and high-latitude ozone declines observed over the last several decades. Analysis of tracer-tracer correlations of H_2O + 2*CH_4 and N_2O indicates that rapid, poleward isentropic transport from the lower tropical stratosphere coupled with diabatic descent between the subtropical and polar jet streams delivers very young air to the high-latitude lowermost stratosphere during winter, while descent of older air from the vortex and subsequent transport to lower latitudes is very limited. From middle to late winter, mixing ratios of H_2O + 2*CH_4 decrease by about 1 ppmv immediately outside the vortex, consistent with rapid transport of the winter phase of the seasonal cycle in water vapor to high latitudes from the lower tropical stratosphere. No evidence of isentropic mixing from the upper tropical troposphere survives in the high-latitude lowermost stratosphere except below 350 K, where markedly higher water vapor mixing ratios indicate mixing from the extratropical troposphere. All of these transport processes pose dynamical and chemical consequences for ozone. Transport from the lower tropical stratosphere (1) exports ozone-poor air to midlatitudes and the subvortex region and (2) distributes elevated water vapor to high latitudes, potentially enhancing halogen-catalyzed ozone destruction through heterogeneous processing in the polar vortex.