首页>
外文期刊>Catalysis science & technology
>One-pot combustion fabrication of grain-like mesoporous intra-heterostructure BixOyClz nanophotocatalyst with substantial solar-light-driven degradation of antibiotic ofloxacin: influence of various fuels
【24h】
One-pot combustion fabrication of grain-like mesoporous intra-heterostructure BixOyClz nanophotocatalyst with substantial solar-light-driven degradation of antibiotic ofloxacin: influence of various fuels
In the present study, a BixOyClz nanophotocatalyst was synthesized via one-pot solution combustion synthesis using various fuels such as glycine, urea, citric acid and sorbitol. Characterization of the photocatalyst was carried out by XRD, FESEM, TEM, PSD, EDX, BET-BJH, UV-vis DRS, PL and pHpzc techniques. The results revealed that a grain-like mesoporous BixOyClz nanophotocatalyst consisting of BiOCl and Bi24O31Cl10 was successfully synthesized using sorbitol. The fabricated nanophotocatalyst was used in the degradation of the antibiotic ofloxacin under simulated solar light. The highest efficiency (82.5%) and reaction rate (k = 0.017 min(-1)) in the photodegradation of the antibiotic ofloxacin were achieved with the grain-like mesoporous nanophotocatalyst synthesized using sorbitol. Studies of the effects of operational parameters such as the pH, catalyst loading and antibiotic concentration showed an increase in the photocatalytic performance of BixOyClz (sorbitol) at a low concentration of the pollutant, at the optimal catalyst dosage (5 g L-1) and in acidic media. High stability after five reaction cycles was observed for the BixOyClz (sorbitol) nanophotocatalyst. Moreover, a reaction mechanism was suggested for the photodegradation of the antibiotic ofloxacin over BixOyClz (sorbitol).
展开▼
机译:在目前的研究中,一个BixOyClz nanophotocatalyst通过锅溶液燃烧合成吗综合使用各种燃料如甘氨酸,尿素,柠檬酸,山梨糖醇。的光催化剂进行XRD、FESEM TEM、PSD、EDX、BET-BJH UV-vis DRS,很难飞》pHpzc技术。很像介孔BixOyClz nanophotocatalystBiOCl和Bi24O31Cl10组成的成功地使用山梨糖醇合成。装配式nanophotocatalyst中使用抗生素的降解氧氟沙星模拟太阳能灯。(82.5%)和反应速率(k = 0.017分钟(1))的光降解抗生素氧氟沙星取得了很像介孔nanophotocatalyst使用山梨糖醇合成。研究操作参数的影响如pH值、催化剂加载和抗生素浓度的增加光催化性能BixOyClz(山梨糖醇)在低浓度的污染物最佳催化剂用量(5 g l - 1)和酸性媒体。观察了BixOyClz(山梨糖醇)nanophotocatalyst。提出的光降解吗抗生素在BixOyClz氧氟沙星(山梨糖醇)。
展开▼